BLACKMONDLAB

PUBLICATIONS

1999

Blackmond, D.G.; Rosner, T.; Neugebauer, T.; Reetz, M.T. Kinetic influences on enantioselectivity for non-diastereopure catalyst mixtures. Angew Chem Int Ed Engl 1999, 38 (15), 2196-2199. PMID: 10425479.

Le Bars, J.; Specht, U.; Bradley, J.S.; Blackmond, D.G. A catalytic probe of the surface of colloidal palladium particles using Heck coupling reactions. Langmuir 1999, 15 (22), 7621-7625.

Blackmond, D.G.; Rosner, T.; Pfaltz, A. Comprehensive kinetic screening of catalysts using reaction calorimetry. Org Process Res Dev 1999, 3 (4), 275-280.

1998

Blackmond, D.G. Kinetic implications of nonlinear effects in asymmetric synthesis. J Am Chem Soc 1998, 120 (51), 13349-13353.

Blackmond, D.G. Reflections on asymmetric catalysis: A kinetic view of enantioselectivity. CaTTech 1998, 3, 17-30.

Siedlaczek, G.; Schwickardi, M.; Kolb, U.; Bogdanovic, B.; Blackmond, D.G. Diastereoselective reductive amination reactions using novel metal–carbon catalysts prepared from inorganic Grignard reagents. Catal Letters 1998, 55 (2), 67-72.

Blackmond, D.G. Non-linear effects in asymmetric catalysis: Implications for organic synthesis strategies. In: Catalysis of organic reactions. Ed. F.E. Herkes. Marcel Dekker, Inc., New York, 1998; pp. 455-466.

Blackmond, D.G. Comments on “Nature of initial transient period during enantioselective hydrogenation on Pt and Pd” by T. Mallat, Z. Bodnar, B. Minder, K. Borszeky, and A. Baiker. J Catal 1998, 176 (1), 267-270.

Bohnen, F.M.; Gamez, A.; Blackmond, D.G. On the implications of hemiketal formation during ethyl pyruvate hydrogenation in alcohol solvents. J Catal 1998, 179 (2), 335-338.

1997

Blackmond, D.G. Mathematical models of nonlinear effects in asymmetric catalysis: New insights based on the role of reaction rate. J Am Chem Soc 1997, 119 (52), 12934-12939.

Sun, Y.; Wang, J.; LeBlond, C.; Reamer, R.A.; Laquidara, J.; Sowa, J.R.; Blackmond, D.G. Kinetic influences on enantioselectivity in asymmetric catalytic hydrogenation. J Organomet Chem 1997, 548 (1), 65-72.

Wang, J.; LeBlond, C.; Orella, C.F.; Sun, Y.; Bradley, J.S.; Blackmond, D.G. Modeling of kinetically coupled selective hydrogenation reactions: Kinetic rationalization of pressure effects on enantioselectivity. In: Studies in surface science and catalysis. Eds. H.U. Blaser; A. Baiker; R. Prins. Elsevier, 1997; Vol. 108, pp. 183-190.

Sun, Y.; Wang, J.; LeBlond, C.; Landau, R.N.; Joseph, L.; Sowa, J.R.; Blackmond, D.G. Kinetic influences on enantioselectivity in asymmetric catalytic hydrogenation. J Mol Catal A Chem 1997, 115 (3), 495-502.

Blackmond, D. Book review of “Principles and practice of heterogeneous catalysis” by J. M. Thomas and W. J. Thomas. J Catal 1997, 171 (1), 349-350.

1996

Sun, Y.; Landau, R.N.; Wang, J.; LeBlond, C.; Blackmond, D.G. A re-examination of pressure effects on enantioselectivity in asymmetric catalytic hydrogenation. J Am Chem Soc 1996, 118 (6), 1348-1353.

Wang, J.; Sun, Y.; LeBlond, C.; Landau, R.N.; Blackmond, D.G. Asymmetric hydrogenation of ethyl pyruvate: Relationship between conversion and enantioselectivity. J Catal 1996, 161 (2), 752-758.

Sun, Y.; Wang, J.; LeBlond, C.; Landau, R.N.; Blackmond, D.G. Asymmetric hydrogenation of ethyl pyruvate: Diffusion effects on enantioselectivity. J Catal 1996, 161 (2), 759-765.

LeBlond, C.; Wang, J.; Larsen, R.D.; Orella, C.J.; Forman, A.L.; Landau, R.N.; Laquidara, J.; Sowa, J.R.; Blackmond, D.G.; Sun, Y.K. Reaction calorimetry as an in-situ kinetic tool for characterizing complex reactions. Thermochim Acta 1996, 289 (2), 189-207.

1995

Sun, Y.; LeBlond, C.; Wang, J.; Blackmond, D.G.; Laquidara, J.; Sowa, J.R., Jr. Observation of a [RuCl2((S)-(-)-tol-binap)]2.N(C2H5)3-catalyzed isomerization-hydrogenation network. J Am Chem Soc 1995, 117 (50), 12647-12648.

Landau, R.N.; Singh, U.; Gortsema, F.; Sun, Y.K.; Gomolka, S.C.; Lam, T.; Futran, M.; Blackmond, D.G. A reaction calorimetric investigation of the hydrogenation of a substituted pyrazine. J Catal 1995, 157 (1), 201-208.

Singh, U.K.; Landau, R.N.; Sun, Y.K.; Leblond, C.; Blackmond, D.G.; Tanielyan, S.K.; Augustine, R.L. Enantioselective catalysis: Influence of conversion and bulk diffusion limitations on selectivity in the hydrogenation of ethyl pyruvate. J Catal 1995, 154 (1), 91-97.

Wang, J.; Oukaci, R.; Wender, I.; Blackmond, D.G. Alcohol synthesis from CO/H2 over Co/Cu/ZnO/Al2O3: In-situ addition of Ch3NO2. J Catal 1995, 153 (1), 100-107.

Blackmond, D.G.; Waghray, A. The Role of alkali promoters in the selective hydrogenation of 3-methyl 2-butenal. In: Catalysis of organic reactions. Eds. M.G. Scaros; M.L. Prunier. Marcel Dekker, Inc., New York, 1995; pp. 295-305.

1994

Landau, R.N.; Blackmond, D.G.; Tung, H.-H. Calorimetric investigation of an exothermic reaction: Kinetic and heat flow modeling. Ind Eng Chem Res 1994, 33 (4), 814-820.

Landau, R.N.; Blackmond, D.G. Scale up heat transfer based on reaction calorimetry. Chem Eng Prog 1994, 90 (11), 43-48.

1993

Waghray, A.; Oukaci, R.; Blackmond, D.G. Selective hydrogenation of α, β-unsaturated aldehydes over supported Ru. In: Studies in surface science and catalysis. Eds. L. Guczi; F. Solymosi; P. Tétényi. Elsevier, 1993; Vol. 75, pp. 2479-2482.

Waghray, A.; Blackmond, D.G. Infrared spectroscopic studies of the adsorption and reaction of 3-methyl-2-butenal over alkali-promoted ruthenium/silica catalysts. J Phys Chem 1993, 97 (22), 6002-6006.

Waghray, A.; Oukaci, R.; Blackmond, D.G. Selective hydrogenation of unsaturated aldehydes over silica- and zeolite-supported metals. In: Catalysis of organic reactions. Eds. J.R. Kosak; T.A. Johnson. Marcel Dekker, Inc., New York, 1993; pp. 569-574.

1992

Waghray, A.; Wang, J.; Oukaci, R.; Blackmond, D.G. Influence of alkali promoters in the selective hydrogenation of 3-methyl-2-butenal over ruthenium/silica catalysts. J Phys Chem 1992, 96 (14), 5954-5959.

Waghray, A.; Oukaci, R.; Blackmond, D.G. Diffusion effects in the hydrogenation of 3-methyl crotonaldehyde over zeolite-supported Ru. Catal Letters 1992, 14 (1), 115-122.

Oukaci, R.; Blackmond, D.G.; Goodwin, J.G., Jr.; Gallaher, G.R. Steady-state isotopic transient kinetic analysis investigation of CO-O2 and CO-NO reactions over a commercial automotive catalyst. In: Catalytic control of air pollution: Mobile and stationary sources. Eds. R.G. Silver; J.E. Sawyer; J.C. Summers. ACS, 1992; Vol. 495, pp. 61-72.

1991

Blackmond, D.G.; Oukaci, R.; Blanc, B.; Gallezot, P. Geometric and electronic effects in the selective hydrogenation of α,β-unsaturated aldehydes over zeolite-supported metals. J Catal 1991, 131 (2), 401-411.

Blackmond, D.G.; Waghray, A.; Oukaci, R.; Blanc, B.; Gallezot, P. Selective hydrogenation of unsaturated aldehydes over zeolite-supported metals. In: Studies in surface science and catalysis. Eds. M. Guisnet; J. Barrault; C. Bouchoule; D. Duprez; G. Pérot; R. Maurel; C. Montassier. Elsevier, 1991; Vol. 59, pp. 145-152.

Cavalcanti, F.A.P.; Oukaci, R.; Wender, I.; Blackmond, D.G. CH3NO2 addition to CO hydrogenation over a Ru/KY catalyst. J Catal 1991, 128 (2), 311-319.

1990

Cavalcanti, F.A.P.; Oukaci, R.; Wender, I.; Blackmond, D.G. Probe molecule studies of CO hydrogenation over Ru/SiO2. J Catal 1990, 123 (1), 260-269.

Cavalcanti, F.A.P.; Oukaci, R.; Wender, I.; Blackmond, D.G. Nitroethane as a probe molecule for CO hydrogenation over Ru/SiO2. J Catal 1990, 123 (1), 270-274.

Blackmond, D.G.; Swid, K.P.; Davis, M.E.; Gallezot, P. The nature of Rh-CO interactions on SAPO-5-supported Rh. J Catal 1990, 122 (2), 247-255.