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Publication List

  1. Liu, W.-B., Schuman, D.P., Yang, Y.-F., Toutov, A.A., Liang, Y., Klare, H.T., Nesnas, N., Oestreich, M., Blackmond, D.G., Virgil, S.C., Banerjee, S., Zare, R.N., Grubbs, R.H., Houk, K.N., Stoltz, B.M., KOt-Bu-Catalyzed Dehydrogenative C–H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study, J. Am. Chem. Soc. 2017, accepted.
  2. Wagner, A.J., Zubarev, D. Yu., Aspuru-Guzik, A., Blackmond, D.G., Chiral Sugars Drive Enantioenrichment in Prebiotic Amino Acid Synthesis, ACS Central Sci., 2017, 3, 322-328.
  3. Wagner, A.J., Blackond, D.G. The Future of Prebiotic Chemistry. ACS Central Sci. (invited First Reactions Essay), 2016, 2, 775-777.
  4. Gherase, D., Hazen, R.M., Krishnamurthy, R., Blackmond, D.G., Mineral-Induced Enantioenrichment of Tartaric Acid. Synlett (Cluster on Prebiotic Chemistry, invited submission) 2017, 28, 89-92.
  5. Shi, Q., Mower, M.P., Blackmond, D.G., Rebek, Jr., J. Molecular Behavior in Small Spaces: Hydrolysis of Diesters in Cavitands. PNAS, 2016, 113, 9199-9203.
  6. Stich, M., Ribó, J.M., Blackmond, D.G., Hochberg, D. Necessary Conditions fort he Emergence of Homochirality via Autocatalytic Self-Replication. J. Chem. Phys. 2016, 145, 074111.
  7. Masseroni, D., Mosca, S., Mower, M.P., Blackmond, D.G., and Julius Rebek, Jr., Cavitands as Reaction Vessels and Blocking Groups for Selective Reactions in Water. Angew. Chemie Int. Ed., 2016, 55, 8290-8293.
  8. Burés, J. Armstrong, A., Blackmond, D.G. Explaining Anomalies in Enamine Catalysis: “Downstream Intermediates” and a New Paradigm for Stereocontrol. Acc. Chem. Res., 2016, 49, 214-222.
  9. Elsila, J.E., Aponte, J.C., Blackmond, D.G., Burton, A.S., Dworkin, J.P., Meteoritic Amino Acids: Diversity in Compositions Reflects Parent Body Histories. ACS Central Sci., 2016, 2, 370-379.
  10. O’Brien, A.G. Luca, O.A., Baran, P.S., Blackmond, D.G. In-Situ FTIR Spectroscopic Monitoring of Electrochemically Controlled Organic Reactions in a Recycle Reactor, Reaction Chemistry & Engineering. 2016, 1, 90-95.
  11. Baxter, R.D, Liang, Y., Hong, X, Brown, T.A., Zare, R.N., Houk, K.N., Baran, P.S., Blackmond, D.G., Mechanistic Insights into Two-Phase Radical C-H Arylations. ACS Central Sci., 2015, 1, 456-462.
  12. Ji, Y., Plata, R.E., Regens, C.S., Hay, M. Schmidt, M., Razler, T., Qui, Y., Geng, P., Xiao, Y. Rosner, T., Eastgate, M.D., Blackmond, D.G. Mono-Oxidation of Bi-dentate Bis-Phosphines in Catalyst Activation: Kinetic and Mechanistic Studies of a Pd/Xantphos-Catalyzed C-H Functionalization. J. Am. Chem. Soc., 2015, 137, 13272-13281.
  13. Blackmond, D.G. Kinetic Profiling of Organic Catalytic Reactions as a Mechanistic Tool. J. Am. Chem. Soc., 2015, 137, 10852-10866. (invited Perspective article).
  14. Ruiz-Castillo, P., Blackmond, D.G., Buchwald, S.L., Rational Ligand Design for the Arylation of Hindered Primary Amines Guided by Reaction Progress Kinetic Analysis. J. Am. Chem. Soc., 2015, 137, 3085-3092.
  15. Mower, M., Blackmond, D.G., Mechanistic Rationalization of Unusual Sigmoidal Kinetic Profiles in the Machetti-De Sarlo Cycloaddition Reaction. J. Am. Chem. Soc., 2015, 137, 2386-2391.
  16. Hawbaker, N., Christiansen, B., Wittgrove, E., Sach, N., Blackmond, D.G., Dispersion in Compartmentalized Flow Systems: Influence of Flow Patterns on Reactivity. OPRD, 2016, 20, 465-473.
  17. Ji, Y., Benkovics, T., Beutner, G.L., Sfouggatakis, C., Eastgate, M.D., Blackmond, D.G. Mechanistic Insights into the Vanadium-Catalyzed Achamatowicz Rearrangement of Furfurol. J. Org. Chem., 2015, 80, 1696-1702.
  18. O’Brien, A.G., Maruyama, A., Inokuma, Y, Fujita, M., Baran, P.S., Blackmond, D.G., Radical C-H Functionalization of Heteroarenes Under Electrochemical Control. Angew. Chemie Int. Ed. 2014, 53, 12062-12065. Hot Paper.
  19. Burès, J.; Armstrong, A.; Blackmond, D.G., Rationalization of an Unusual Solvent-Induced Inversion of Enantiomeric Excess in Organocatalytic Selenylation of Aldehydes. Angew. Chemie Int. Ed. 2014, 53, 8700-8704.
  20. Ji, Y.; Blackmond, D.G. The Role of Reversibility in the Enantioselective Conjugate Addition of α,α-Disubstituted Aldehydes to Nitro-Olefins Catalyzed by Primary Amine Thioureas. Catal. Sci. Tech. 2014, 4, 3505-3509.
  21. Gherase, D.; Conroy, D.; Matar, O.K.; Blackmond, D.G., Experimental and Theoretical Study of the Emergence of Single Chirality in Attrition-Enhanced Deracemization. Cryst. Growth Des. 2014, 14, 928-937.
  22. O’Hara, F.; Baran, P.S.; Blackmond, D.G. Radical-Based Regioselective C−H Functionalization of Electron-Deficient Heteroarenes: Scope, Tunability, and Predictability. J. Am. Chem. Soc. 2013, 135, 12122-12134.
  23. Burès, J.; Armstrong, A.; Blackmond, D.G. The Interplay of Thermodynamics and Kinetics in Dictating Organocatalytic Reactivity and Selectivity. Pure and App. Chem. 2013, 85, 1919-1934.
  24. Baxter, R.D.; Blackmond, D.G. In-Situ Kinetic Studies of the Trifluoromethylation of Caffeine with Zn(SO2CF3)2. Tetrahedron. 2013, 69, 5604-5608.
  25. Hein, J.E.; Gherase, D.; Blackmond, D.G. Chemical and Physical Models for the Origin of Biological Homochirality. Top. Curr. Chem. 2013, 333, 83-108.
  26. Hein, J.E.; Cao, B.H.; Viedma, C.; Kellogg, R.M.; Blackmond, D.G. Pasteur’s Tweezers Revisited: On the Mechanism of Attrition-Enhanced Deracemization and Resolution of Chiral Conglomerate Solids. J. Am. Chem. Soc. 2012, 134, 12629-12636.
  27. Gehring, T.; Quaranta, M.; Odell, B.; Blackmond, D.G.; Brown, J.M. Observation of a Transient Intermediate in Soai’s Asymmetric Autocatalysis: Insights from 1H NMR Turnover in Real Time. Angew. Chemie Int. Ed. 2012, 51, 9539-9542.
  28. Burès, J.; Armstrong, A.; Blackmond, D.G. Curtin-Hammett Paradigm for Stereocontrol in Organocatalysis by Diarylprolinol Ether Catalysts. J. Am. Chem. Soc. 2012, 134, 6741-6750.
  29. Baxter, R.D.; Sale, D.; Engle, K.; Yu, J.-Q.; Blackmond, D.G. Mechanistic Rationalization of Unusual Kinetics in Pd-Catalyzed C–H Olefination. J. Am. Chem. Soc. 2012, 134, 4600-4606.
  30. Hein, J.E.; Blackmond, D.G. On the Origin of Single Chirality of Amino Acids and Sugars in Biogenesis. Acc. Chem. Res. 2012, 45, 2045-2054.
  31. Fujiwara, Y.; Dixon, J.; Rodriguez, R.; Baxter, R.D.; Dixon, D.; Collins, M.; Blackmond, D.G.; Baran, P.S. A New Reagent for Direct Difluoromethylation. J. Am. Chem. Soc. 2012, 134, 1494-1497.
  32. Burès, J.; Armstrong, A.; Blackmond, D.G. Kinetic Correlation Between Aldehyde/Enamine Stereoisomers in Reactions Between Aldehydes With α-Stereocenters and Chiral Pyrrolidine-Based Catalysts. Chemical Sci. 2012, 3, 1273-1277.
  33. Hein, J.E.; Burès, J.; Lam, Y.-H.; Hughes, M.; Houk, K.N.; Armstrong, A.; Blackmond, D.G. Enamine Carboxylates as Stereodefining Intermediates in Prolinate Catalysis. Org. Lett., 2011, 13, 5644-5647.
  34. Hein, J.E.; Tse, E.; Blackmond, D.G. A Route to Enantiopure RNA from Nearly Racemic Precursors. Nature Chemistry. 2011, 3, 704-706.
  35. Hein, J.E.; Armstrong, A.; Blackmond, D.G. Kinetic Profiling of Prolinate-Catalyzed α-Amination of Aldehydes. Org. Lett. 2011, 13, 4300-4303.
  36. Ji, Y.N.; Bruekl, T.; Baxter, R.D.; Fujiwara, Y.; Seiple, I.B.; Su, S.; Blackmond, D.G.; Baran, P.S. Innate C-H Trifluoromethylation of Heterocycles. PNAS. 2011, 108, 14411-14415.
  37. Burès, J.; Armstrong, A.; Blackmond, D.G. Mechanistic Rationalization of Organocatalyzed Conjugate Addition of Linear Aldehydes to Nitro-Olefins. J. Am. Chem. Soc. 2011, 133, 8822-8825.
  38. Blackmond, D.G. The Origin of Biological Homochirality. Royal Society Phil. Trans. B. 2011, 366, 2878-2884.
  39. Ferretti, A.; Brennan, C.; Blackmond, D.G. Reservoir Catalysis: Rationalization of Anomalous Reaction Orders in Pd-Catalyzed Amination of Aryl Halides. Inorganica Chim. Acta. 2011, 369, 292-295.
  40. Quaranta, M.; Gehring, T.; Odell, B.; Brown, J.M.; Blackmond, D.G. Unusual Inverse Temperature Dependence on Reaction Rate in the Asymmetric Autocatalytic Alkylation of Pyrimidyl Aldehydes. J. Am. Chem. Soc. 2010, 132, 15104-15107.
  41. Blackmond, D.G.; Moran, A.; Hughes, M.; Armstrong, A. Unusual Reversal of Enantioselectivity in the Proline-Mediated α-Amination of Aldehydes Induced by Tertiary Amine Additives. J. Am. Chem. Soc. 2010 132, 7598-7599.
  42. Blackmond, D.G. Kinetic Aspects of Nonlinear Effects in Asymmetric Synthesis, Catalysis, and Autocatalysis. Tetrahedron Asymm. 2010, 21, 1630-1634.
  43. Blackmond, D.G. The Origin of Biological Homochirality. In The Origin of Life, ed. no.; Deamer, D.; Szostak, J.W., Cold Spring Harbor Laboratory Press, 2010.
  44. Valera, F.E.; Quaranta, M.; Moran, A.; Blacker, J.; Armstrong, A.; Cabral, J.T.; Blackmond, D.G. The Flow’s the Thing…Or Is It? Assessing the Merits of Homogeneous Reactions in Flask and Flow. Angew. Chemie Int. Ed, 2010, 49, 2478-2485.
  45. Viedma, C.; Verkuijl, B.J.V.; Ortiz, J.E.; de Torres, T.; Kellogg, R.M.; Blackmond, D.G. Solution-Phase Racemization in the Presence of an Enantiopure Solid Phase. Chem. Eur. J. 2010, 16, 4932-4937.
  46. Zotova, N.; Moran, A.; Armstrong, A.; Blackmond, D.G. A Coherent Mechanistic Rationale for Additive Effects and Autoinductive Behavior in Proline-Mediated Reactions. Adv. Synth. Catal. 2009, 351, 2765-2769.
  47. Zotova, N.; Broadbelt, L.J.; Armstrong, A.; Blackmond, D.G. Kinetic and Mechanistic Studies of Proline-Mediated Direct Intermolecular Aldol Reactions. Bioorg. Med. Chem. Lett. 2009 19, 3934-3937.
  48. Blackmond, D.G. An Examination of the Role of Autocatalytic Cycles in the Chemistry of Proposed Primordial Reactions. Angew. Chemie Int. Ed. 2009, 48, 386-390.
  49. Blackmond, D.G. ‘If Pigs Could Fly’ Chemistry: A Tutorial on the Principle of Microscopic Reversibility. Angew. Chemie Int. Ed. 2009, 48, 2648-2654.
  50. Blackmond, D.G. Challenging the Concept of Recycling as a Mechanism for the Evolution of Homochirality in Chemical Reactions. Chirality. 2009, 21, 359-362.
  51. Klussman, M.; Blackmond, D.G. Origin of Homochirality. Ch. 7 in Chemical Evolution II: From the Origins of Life to Modern Society. ed.; Zaikowski, L.; Friedrich, J.; Seidel, S.R., Eds.; OUP USA ACS Symposium Series, 2009, 133-145 (with M. Klussmann).
  52. Viedma, C.; Ortiz, J.E.; de Torres, T.; Izumi, T.; Blackmond, D.G. Evolution of Solid-Phase Homochirality for a Proteinogenic Amino Acid. J. Am. Chem. Soc. 2008, 130, 15274-15275.
  53. Blackmond, D.G. Response to Comments on ‘A Re-Examination of Reversibility in Reaction Models for the Spontaneous Emergence of Homochirality’. J. Phys. Chem. 2008, 112, 9553-9555.
  54. Blackmond, D.G.; Matar, O.K. Re-Examination of Reversibility in Reaction Models for the Spontaneous Emergence of Homochirality. J. Phys. Chem. 2008, 112, 5098-5104.
  55. Ferretti, A.C.; Mathew, J.S.; Ashworth, I.; Purdy, M.; Brennan, C.; Blackmond, D.G. Mechanistic Inferences Derived from Competitive Catalytic Reactions: Pd(binap)-Catalyzed Amination of Aryl Halides. Adv. Synth. Catal. 2008, 350, 1007-1012.
  56. Noorduin, W.L.; Izumi, T.; Millemaggi, A.; Leeman, M.; Meekes, H.; Enckevort, W.J.; Kellogg, R.M.; Kaptein, B.; Vlieg, E.; Blackmond, D.G. Emergence of a Single Solid Chiral State from a Nearly Racemic Amino Acid Derivative. J. Am. Chem. Soc. 2008, 130, 1158-1159.
  57. Zotova, N., Iwamura, H., Mathew, S.P. Blackmnd, D.G., “Reaction Progress Kinetic Analysis: A Powerful Methodology for Streamlining Pharmaceutical Reaction Steps” in Trends in Process Chemistry. ed. By T. Braish and K. Gadasamatti, CRC Press: New York, 2008, 455-464.
  58. Zotova, N.; Franzke, A.; Armstrong, A.; Blackmond, D.G. Clarification of the Role of Water in Proline-Mediated Aldol Reactions. J. Am. Chem. Soc. 2007, 129, 15100-15101.
  59. Blackmond, D.G. Response to ‘Comments on a Possible Transition to Solid-Phase Homochirality’. Chem. Eur. J. 2007, 13, 10306-10311.
  60. Klussmann, M.; Izumi, I.T.; White, A.J.P.; Armstrong, A.; Blackmond, D.G. Emergence of Solution Phase Homochirality via Crystal Engineering of Amino Acids. J. Am. Chem. Soc. 2007, 129, 7657-7660.
  61. Ferretti, A.C.; Mathew, J.S.; Blackmond, D.G. Reaction Calorimetry as a Tool for Understanding Reaction Mechanisms: Application to Pd-Catalyzed Reactions. Ind. Eng. Chem. Res. 2007, 46, 8584-8589.
  62. Blackmond, D.G.; Armstrong, A.; Coombe, V.; Wells, A. Water in Organocatalytic Processes: Debunking the Myths. Angew. Chemie Int. Ed. 2007, 46, 3798-3800.
  63. Blackmond, D.G.; Klussmann, M. Spoilt for Choice: Assessing Phase Behavior Models for the Evolution of Homochirality. Chem. Commun. 2007, 3990-3996.
  64. Blackmond, D.G. Chiral Amnesia as a Driving Force for Solid-Phase Homochirality. Chem. Eur. J. 2007, 13, 3290-3295.
  65. Phua, P.H.; Mathew, S.P.; White, A.J.P.; de Vries, J.G.; Blackmond, D.G.; Hii, K.K. Elucidating the Mechanism of the Asymmetric Aza-Michael Reaction. Chem. Eur. J. 2007, 13, 4602-4613.
  66. Klussmann, M.; Blackmond, D.G. Investigating the Origin of Biomolecular Homochirality. AIChE J. 2007, 53, 2-8.
  67. Klussmann, M.; Iwamura, H.; Mathew, S.P.; Wells, Jr., D.H.; Pandya, U.; Armstrong, A.; Blackmond, D.G. Thermodynamic Control of Asymmetric Amplification in Amino Acid Catalysis. Nature. 2006, 441, 621-623.
  68. Klussmann, M.; White, A.J.P.; Armstrong, A.; Blackmond, D.G. Rationalization and Prediction of Solution Enantiomeric Excess in Ternary Phase Systems. Angew. Chemie Int. Ed. 2006, 45, 7985-7989.
  69. Klussmann, M.; Mathew, S.P.; Iwamura, H.; Wells, Jr., D.H.; Armstrong, A.; Blackmond, D.G. Kinetic Rationalization of Nonlinear Effects in Asymmetric Catalysis Based on Phase Behavior. Angew. Chemie Int. Ed. 2006, 45, 7989-7992.
  70. Mathew, S.P.; Klussmann, M.; Iwamura, H.; Wells, Jr., D.H.; Armstrong, A.; Blackmond, D.G. A Mechanistic Rationalization of Unusual Kinetic Behavior in Proline-Mediated C-O and C-N Bond-Forming Reactions. Chem. Commun. 2006, 4291-4293.
  71. Blackmond, D.G.; Schultz, T.; Mathew, J.S.; Loew, C.; Rosner, T.; Pfaltz, A. Comprehensive Kinetic Screening of Palladium Catalysts for Heck Reactions. Synlett. 2006, 18, 3135-3139.
  72. Blackmond, D.G.; Hodnett, N.; Lloyd-Jones, G.C. Mechanistic Implications of Pseudo Zero Order Kinetics in Kinetic Resolutions. J. Am. Chem. Soc., 2006, 128, 7450-7451.
  73. Mathew, J.S.; Klussmann, M.; Iwamura, H.; Valera, F.; Futran, A.; Emanuelsson, E.A.C.; Blackmond, D.G. Investigations of Pd-Catalyzed ArX Coupling Reactions Informed by Reaction Progress Kinetic Analysis. J. Org. Chem. 2006, 71, 4711-4722.
  74. Shekhar, S.; Ryberg, P.; Hartwig, J.F.; Mathew, J.S.; Blackmond, D.G.; Strieter, E.R.; Buchwald, S.L. Reevaluation of the Mechanism of the Amination of Aryl Halides Catalyzed by BINAP-Ligated Palladium Complexes. J. Am. Chem. Soc. 2006, 128, 3584-3591.
  75. Blackmond, D.G. Mechanistic Study of the Soai Autocatalytic Reaction Informed By Kinetic Analysis. Tetr. Asymm. 2006, 17, 584-589.
  76. Blackmond, D.G. Kinetic Investigations of the Soai Autocatalytic Reaction. In Asymmetric Synthesis: The Basics. ed. Bräse, S.; Christmann, M., Wiley, NY, 2006, 181-185.
  77. Blackmond, D.G.; Ropic, M.; Stefinovic, M. Kinetic Studies of the Asymmetric Transfer Hydrogenation of Imines with Formic Acid Catalyzed by Rh-Diamine Catalysts. Org. Process Res. Dev. 2006, 10, 457-463.
  78. Blackmond, D.G. Kinetic Investigations of the Role of Catalysis in The Origin of Biological Homochirality. Strem Chemiker. vol XXII, 2005, p.14-23.
  79. Blackmond, D.G. Reaction Progress Kinetic Analysis: A Powerful Methodology for for Mechanistic Studies of Complex Catalytic Reactions. Angew. Chemie Int. Ed. 2005, 44, 4302-4320.
  80. Mathew, S.P.; Gunathilagan, S.; Roberts, S.M.; Blackmond, D.G. Mechanistic Insights from Reaction Progress Kinetic Analysis of the Polypeptide-Catalyzed Epoxidation of Chalcone. Org. Lett. 2005, 7, 4847-4850.
  81. Reetz, M.T.; Meiswinkel, A.; Mehler, G.; Angermund, K.; Graf, M.; Thiel, W.; Mynott, R.; Blackmond, D.G. Why Are BINOL-Based Monophosphites Such Efficient Ligands in Rh-Catalyzed Asymmetric Olefin Hydrogenation? J. Am. Chem. Soc. 2005, 127, 10305-10313.
  82. Arseniyadis, S.; Subhash, P.V.; Valleix, A.; Mathew, S.P.; Blackmond, D.G.; Wagner, A.; Mioskowski, C. Tuning the Enantioselective N-Acetylation of Racemic Amines: A Spectacular Salt Effect. J. Am. Chem. Soc. 2005, 127, 6138-6139.
  83. Strieter, E.R.; Blackmond, D.G.; Buchwald, S.L. The Role of Chelating Diamine Ligands in the Goldberg Reaction: A Kinetic Study on the Copper-Catalyzed Amidation of Aryl Iodides. J. Am. Chem. Soc. 2005, 127, 4120-4121.
  84. Iwamura, H.; Wells. Jr., D.H.; Mathew, S.P.; Klussmann, M.; Armstrong, A.; Blackmond, D.G. Probing the Active Catalyst in Product-Accelerated Proline-Mediated Reactions. J. Am. Chem. Soc. 2004, 126, 16312-16313.
  85. Iwamura, H.; Mathew, S.P.; Blackmond, D.G. In-Situ Catalyst Improvement in the Proline-Mediated α-Amination of Aldehydes. J. Am. Chem. Soc. 2004, 126, 11770-11771.
  86. Mathew, S.P.; Iwamura, H.; Blackmond, D.G. Amplification of Enantiomeric Excess in a Proline-Mediated Reaction. Angew. Chemie Int. Ed. 2004, 43, 3317-3321.
  87. Blackmond, D.G. Asymmetric Autocatalysis and its Implications for the Origin of Homochirality. PNAS. 2004, 101, 5732-5736.
  88. Buono, F.G.; Iwamura, H.; Blackmond, D.G. Physical and Chemical Rationalization for Asymmetric Amplification in Autocatalytic Reactions. Angew. Chemie Int. Ed. 2004, 43, 2099-2103.
  89. Nielsen, L.P.; Stevenson, C.P.; Blackmond, D.G.; Jacobsen, E.N. Mechanistic Investigation Leads to a Synthetic Improvement in the Hydrolytic Kinetic Resolution of Terminal Epoxides. J. Am. Chem. Soc. 2004, 126, 1360-1362.
  90. LeBars, J.; Dini, S.; Hawkins, J.M.; Blackmond, D.G. Mechanistic Insights into Anomalous Kinetic Behavior in the Hydrogenation of a Substituted Nitrobenzene. Adv. Synth. Catal. 2004, 346, 943-946.
  91. Richards, S.; Ropic, M.; Blackmond, D.G.; Walmsley, A. Quantitative Determination of the Catalysed Asymmetric Transfer Hydrogenation of 1-Methyl-6,7-Dimethoxy-3,4-Dihydroisoquinoline Using In Situ FTIR and Multivariate Curve Resolution. Analytica Chim. Acta. 2004, 519, 1-9.
  92. Strieter, E.R.; Blackmond, D.G.; Buchwald, S.L. Insights into the Origin of High Activity and Stability of Catalysts Derived From Bulky, Electron-Rich Monophosphinobiaryl Ligands in the Pd-Catalyzed C-N Bond Formation. J. Am. Chem. Soc. 2003, 125, 13978-13980.
  93. Buono, F.; Blackmond, D.G. Kinetic Evidence for a Tetrameric Transition State in the Asymmetric Alkylation of Pyrimidyl Aldehyes. J. Am. Chem. Soc. 2003, 125, 8978-8979.
  94. Singh, U.K.; Strieter, E.R.; Blackmond, D.G.; Buchwald, S.L. Mechanistic Insights into the Pd(BINAP)-Catalyzed Amination of Aryl Bromides: Kinetic Studies Under Synthetically Relevant Conditions. J. Am. Chem. Soc. 2002, 124, 14104-14114.
  95. Buono, F.; Walsh, P.J.; Blackmond, D.G. Rationalization of Anomalous Nonlinear Effects in the Alkylation of Substituted Benzaldehydes. J. Am. Chem. Soc. 2002, 124, 13652-13653.
  96. Blackmond, D.G. Requiem for the Rate Equation? Catal. Lett. 2002, 83, 133-136.
  97. Blackmond, D.G. Description of the Condition for Asymmetric Amplification in Autocatalytic Reactions. Adv. Synth. Catal. 2002, 334, 156-158.
  98. Blackmond, D.G; McMillan, C.R.; Ramdeehul, S.; Schorm, A.; Brown, J.M. Origins of Asymmetric Amplification in Autocatalytic Alkylzinc Additions. J. Am. Chem. Soc. 2001, 123, 10103-10104.
  99. Blackmond, D.G. Kinetic Resolution Using Enantioimpure Catalysts: Mechanistic Considerations of Complex Rate Laws. J. Am. Chem. Soc. 2001, 123, 545-53.
  100. Rosner, T.; Pfaltz, A.; Blackmond, D.G. Observation of Unusual Kinetics in Heck Reactions of Aryl Halides: The Role of Non-Steady-State Catalyst Concentration. J. Am. Chem. Soc. 2001, 123, 4621-4622.
  101. Rosner, T.; Le Bars, J.; Pfaltz, A.; Blackmond, D.G. Experimental and Theoretical Kinetic Studies of Heck Reactions: The Role of Dimeric Pd Species. J. Am. Chem. Soc. 2001, 123, 1848-1855.
  102. Le Bars, J.; Häußner, T.; Lang, J.; Pfaltz, A.; Blackmond, D.G. A Scale-Transparent Reaction Calorimetric Assay For Rapid Catalyst Selection. Adv. Synth. Catal. 2001, 2, 207-214.
  103. Rosner, T.; Sears, P.J.; Nugent, W.A.; Blackmond, D.G. Kinetic Investigations of Product Inhibition in the Amino Alcohol-Catalyzed Asymmetric Alkylation of Benzaldehyde with Diethylzinc. Organic Letters. 2000, 2, 2511-2513.
  104. Blackmond, D.G. Kinetic Aspects of Nonlinear Effects in Asymmetric Catalysis. Acc. Chem. Res. 2000, 33, 402-411.
  105. Blackmond, D.G.; Lightfoot, A.; Pfaltz, A.; Rosner, T.; Schnider, P.; Zimmermann, N. Enantioselective Hydrogenation of Olefins With Phosphinooxazoline-Iridium Catalysts. Chirality. 2000, 12, 442-449.
  106. Blackmond, D.G.; Rosner, T.; Neugebauer, T.; Reetz, M.T.; Kinetic Influences on Enantioselectivity for Non-Diastereopure Catalyst Mixtures. Angew. Chemie Int. Ed. Eng. 1999, 38, 2196-2199.
  107. Le Bars, J.; Specht, U.; Bradley, J.S.; Blackmond, D.G. A Catalytic Probe of the Surface of Colloidal Palladium Particles Using Heck Coupling Reactions. Langmuir. 1999, 15, 7621-7625.
  108. Blackmond, D.G.; Rosner, T.; Pfaltz A. Comprehensive Kinetic Screening of Catalysts Using Reaction Calorimetry. Org. Proc. Research and Dev. 1999, 3, 275-280.
  109. Blackmond, D.G. Kinetic Implications of Nonlinear Effects in Asymmetric Synthesis. J. Amer. Chem. Soc. 1998, 120, 13349-13353.
  110. Blackmond, D.G. Reflections on Asymmetric Catalysis: A Kinetic View of Enantioselectivity. CaTTech. 1998, 3, 17-30.
  111. Siedlaczek, G.; Schwickardi, M.; Kolb, U.; Bogdanovic, B.; Blackmond, D.G. Diastereoselective Reductive Amination Reactions Using Novel Metal-Carbon Catalysts Prepared from Inorganic Grignard Reagents. Catal. Lett. 1998, 55, 67-72.
  112. Blackmond, D.G. Non-Linear Effects in Asymmetric Catalysis: Implications for Synthetic Organic Strategies. In Catalysis of Organic Reactions. ed. Herkes, F.E., Marcel Dekker, Inc., New York: 1998, 455.
  113. Blackmond, D.G. Comments on ‘Nature of Initial Transient Period During Enantioselective Hydrogenation on Pt and Pd’. J. Catal. 1998, 176, 267-270.
  114. Bohnen, F.M.; Gamez, A.; Blackmond, D.G. On the Implications of Hemiketal Formation during Ethyl Pyruvate Hydrogenation in Alcohol Solvents. J. Catal. 1998, 179, 335-338.
  115. Blackmond, D.G. Mathematical Models of Nonlinear Effects in Asymmetric Catalysis: New Insights Based on the Role of Reaction Rate. J. Amer. Chem. Soc. 1997, 119, 12934-12939.
  116. Sun, Y.; Wang, J.; LeBlond, C.; Reamer, R.A.; Laquidara, J.; Sowa, J.R.; Blackmond, D.G. Kinetic Influences on Enantioselectivity in Asymmetric Catalytic Hydrogenation. J. Organometallic Chem. 1997, 548, 65-72.
  117. Wang, J.; Sun, Y.; LeBlond, C.; Bradley, J.S.; Blackmond, D.G. Modeling of Kinetically Coupled Selective Hydrogenation Reactions: Kinetic Rationalization of Pressure Effects on Enantioselectivity. Stud. Surf. Sci. Catal., Elsevier, Amsterdam, 1997, 183-190.
  118. Sun, Y.; Wang, J.; LeBlond, C.; Landau, R.N.; Laquidara, J.; Sowa, J.R.; Blackmond, D.G. Kinetic Influences on Enantioselectivity in Asymmetric Catalytic Hydrogenation. J. Molecular Catalysis A. 1997, 115, 495-502.
  119. Sun, Y.; Landau, R.N.; Wang, J.; LeBlond, C.; Blackmond, D.G. A Re-Examination of Pressure Effects on Enantioselectivity in Asymmetric Catalytic Hydrogenation. J. Am. Chem. Soc. 1996, 118, 1348-1353.
  120. Wang, J.; Sun, Y.; LeBlond, C.; Landau, R.N.; Blackmond, D.G. Asymmetric Hydrogenation of Ethyl Pyruvate Over Pt: Relationship Between Conversion and Enantioselectivity. J. Catalysis. 1996, 161, 752-758.
  121. Sun, Y.; Wang, J.; LeBlond, C.; Landau, R.N.; Blackmond, D.G. Asymmetric Hydrogenation of Ethyl Pyruvate: Diffusion Effects on Enantioselectivity. J. Catalysis. 1996, 161, 759-765.
  122. LeBlond, C.; Larsen, R.; Orella, C.; Forman, A.; Landau, R.N.; Laquidara, J.; Sowa, J.R Blackmond, D.G. Reaction Calorimetry as a Powerful Tool for Characterizing Complex Reactions. Thermochim. Acta. 1996, 289, 189-207.
  123. Sun, Y.; LeBlond, C.; Wang, J.; Blackmond, D.G. Laquidara, J.; Sowa, J.R. Observation of a [RuCl2(S-)-tolyl-binap]2.N(C2H5)3-Catalyzed Isomerization-Hydrogenation Network. J. Am. Chem. Soc. 1995, 117, 12647-12648.
  124. Landau, R.N.; Singh, U.K.; Gortsema, F.P.; Sun, Y.; Gomolka, S.C.; Lam, T.; Futran, M.; Blackmond, D.G. A Reaction Calorimetric Investigation of Kinetics and Mass Transfer Considerations in the Hydrogenation of a Substituted Pyrazine. J. Catalysis. 1995, 157, 201-208.
  125. Singh, U.K.; Landau, R.N.; Sun, Y.; LeBlond, C.; Blackmond, D.G.; Tanielyan, S.; Augustine, R.L.; Enantioselective Catalysis: Influence of Conversion and Bulk Diffusion Limitations on Selectivity in the Hydrogenation of Ethyl Pyruvate. J. Catalysis. 1995, 154, 91-97.
  126. Wang, J.; Oukaci, R.; Wender, I.; Blackmond, D.G. Alcohol Synthesis from CO/H2 Over Co/Cu/ZnO/Al2O3: In-Situ Addition of CH3NO2. J. Catalysis. 1995, 153, 100-107.
  127. Landau, R.N.; Blackmond, D.G.; Tung, H.-H.; Calorimetric Investigation of an Exothermic Reaction: Kinetic and Heat Flow Modeling. Ind. Eng. Chem. Res. 1994, 33, 814-820.
  128. Blackmond, D.G.; Waghray, A. The Role of Alkali Promoters in the Selective Hydrogenation of 3-Methyl 2-Butenal. in Catalysis of Organic Reactions. ed. M.G. Scaros and M.L. Prunier, Marcel Dekker, Inc., New York, 1994, p. 295-305 (with A. Waghray).
  129. “Selective Hydrogenation of Unsaturated Aldehydes over SiO2- and Zeolite-Supported Metals” in Catalysis of Organic Reactions. ed. by J.R. Kosak and T.A. Johnson, Marcel Dekker, Inc., New York, 1994, p. 569 (with A. Waghray and R. Oukaci).
  130. Waghray, A.; Blackmond, D.G. In-Situ Infrared Spectroscopic Monitoring of the Adsorption and Reaction of 3-Methyl 2-Butenal over Ru/SiO2 Catalysts. J. Phys. Chem. 1993, 97, 6002-6006.
  131. Waghray, A.; Oukaci, R.; Blackmond, D.G. Selective Hydrogenation of α, β-Unsaturated Aldehydes over Supported Ru. In New Frontiers in Catalysis, Akademiai Kiado, Budapest, 1993, p. 2479-2482.
  132. Waghray, A.; J. Wang, J.; Oukaci, R.; Blackmond, D.G. The Influence of Alkali Promoters in the Selective Hydrogenation of 3-Methyl 2-Butenal over Ru/SiO2 Catalysts. J. Phys. Chem. 1992, 96, 5954-5959.
  133. Waghray, A.; Oukaci, R.; Blackmond, D.G. Diffusion Effects in Gas-Phase Selective Hydrogenation Reactions Over Zeolite-Supported Ru. Catal. Letters. 1992, 14, 115-122.
  134. "Steady-State Isotopic Transient Kinetic Analysis Investigation of CO-O2 and CO-NO Reactions over a Commercial Automotive Catalyst" in Catalytic Control of Air Pollution: Mobile and Stationary Sources. ed. by R.G. Silver, J.E. Sawyer, and J.C. Summers, American Chemical Society, 1992, 61-72 (with R. Oukaci, J.G. Goodwin, Jr., and G.R. Gallaher).
  135. Blackmond, D.G.; Oukaci, R.; Blanc, B.; Gallezot, P.; Geometric and Electronic Effects in the Selective Hydrogenation of α, β Unsaturated Aldehydes over Zeolite-Supported Metals. J. Catalysis. 1991, 131, 401-411.
  136. Waghray, A.; Oukaci, R.; Blanc, B.; Gallezot, P.; Blackmond, D.G. “Selective Hydrogenation of Unsaturated Aldehydes Over Zeolite-Supported Metals” in Heterogeneous Catalysis and Fine Chemicals II, ed. by M. Guisnet et al., Elsevier, Amsterdam, 1991, p. 145-152.
  137. Cavalcanti, F.A.P.; Oukaci, R.; Wender, I.; Blackmond, D.G. CH3NO2 Addition to CO Hydrogenation over a Ru/KY Catalyst. J. Catalysis. 1991, 128, 311-319.
  138. Cavalcanti, F.A.P.; Oukaci, R.; Wender, I.; Blackmond, D.G. Probe Molecule Addition to CO Hydrogenation over Ru/SiO2. J. Catalysis. 1990, 123, 260-269.
  139. Cavalcanti, F.A.P.; Oukaci, R.; Wender, I.; Blackmond, D.G. Nitroethane as a Probe Molecule for CO Hydrogenation Over Ru/SiO2. J. Catalysis. 1990, 123, 270-274.
  140. Blackmond, D.G.; Swid, K.P.; Davis, M.E.; Gallezot, P. The Nature of Rh-CO Interactions on SAPO-5-Supported Rh. J. Catalysis. 1990, 122, 247-255.
  141. Blackmond, D.G.; Sayari, A.; Wender, I. Chemical Trapping of CO/H2 Surface Species. Chemical Communications of the Hungarian Academy of Sciences. 1989, 70, 89-96.
  142. Blackmond, D.G. Metal Clusters in Catalysis. AIChE J. 1988, 34, 173-174.
  143. "The Effect of the Addition of Aklylating Agents on Model Supported Metal Clusters" in Catalysis: Theory to Practice, Proc. 9th International Congr. Catal., Vol. 2 (C1 Chemistry), ed. by M.J. Phillips and M. Ternan, Chemical Institute of Canada, 1988, 792-799 (with A. Erdem-Senatalar and I. Wender).
  144. "The Effects of Alkali Promoters on the Adsorptive Properties of Rh/SiO2 Catalysts" in Studies in Surface Science and Catalysis, Catalysis Today. Vol. 38, Elsevier, Amsterdam, 1988, 33-42 (with S. Kesraoui).
  145. Cavalcanti, F.A.P.; Blackmond, D.G.; Oukaci, R.; Sayari, A.; Erdem-Senatalar, A.; Wender, I. In-Situ Chemical Trapping of CO/H2 Surface Species. J. Catalysis. 1988, 113, 1-12.
  146. Ciocco, M.V.; Blackmond, D.G. Support and Alkali Promotion Effects on the Surface Chemistry of Ni/SiO2 Catalysts. Appl. Catalysis. 1988, 44, 105-116.
  147. Oukaci, R.; A. Sayari, A.; Goodwin, Jr., J.G.; Blackmond, D.G. The Implications of Metal-Support Interactions on Chemisorption Characterization of Supported Metal Catalysts. In Metal-Support Interactions in Catalysis, Sintering and Redispersion, ed. by S. A. Stevenson, J.A. Dumesic, R.T.K. Baker and E. Ruckenstein, van Nostrand Reinhold Co., Inc., New York, 1987, 19-33, 112-120.
  148. Kesraoui, S.; Oukaci, R.; Blackmond, D.G. Adsorption and Reaction of CO and H2 on K-Promoted Rh/SiO2 Catalysts. J. Catalysis. 1987, 105, 432-444.
  149. Williams, J.A.; Blackmond, D.G.; Wender, I. Chemical Trapping of CO/H2 Surface Species. Div. Fuel Chem. Prepr. 192nd Annual ACS Meeting, Anaheim, 1986.
  150. Williams, J.A.; Kesraoui, S.; Blazewick, D.S., Blackmond, D.G.; The Effects of Cs Promotion on Rh/Al2O3 Catalysts. J. Catalysis. 1986, 101, 496-504.
  151. Blackmond, D.G.; Ko, E.I. CO Adsorption on Supported Ni Catalysts: Support Effects and Carbonyl Formation. J. Catalysis. 1985 94, 343-352.
  152. Blackmond, D.G.; Ko, E.I. Structural Sensitivity of CO Adsorption and H2/CO Coadsorption on Ni/SiO2 Catalysts. J. Catalysis. 1985, 96, 210-221.
  153. Blackmond, D.G.; Ko, E.I. Preparation and Characterization of Well-Defined Ni/SiO2 Catalysts. Appl. Catalysis. 1984, 13, 49-68.
  154. Blackmond, D.G. Rogan, R.H.; Ko, E.I.; Reduction Characteristics of Supported Ni Catalysts. Proceedings, 12th Annual Conference of the North American Thermal Society, Williamsburg, VA, 1983, 412-415.
  155. Blackmond, D.G.; Goodwin, Jr., J.G.: Lester, J.E. In-situ FTIR Study of HY Cracking Catalysts: Coke Formation and the Nature of the Active Sites. J. Catalysis. 1982, 78, 34-43.
  156. Blackmond, D.G.; Goodwin, Jr., J.G. The Effect of H2 on the Adsorption and Reaction of 1-Hexene on HY Cracking Catalysts. J. Catalysis. 1982, 78, 247-252.
  157. Blackmond, D.G., Lester, J.E.; Goodwin, Jr., J.G.; Application of Fourier Transform IR Spectroscopy to Studies of Coke Formation on Cracking Catalysts" in Progress in Catalyst Deactivation. ed. by J. Figueirado, Martinus Nijhoff Publishers, The Hague, 1982, pp. 93- 102.
  158. Blackmond, D.G.; Goodwin, Jr., J.G. Zeolite Support Effects on CO-Ru Interactions. Chem. Communications. 1981, 125-126.

Last Updated: 05/02/2017

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