71.   W. R. Roush and B. B. Brown, "Diastereoselective Synthesis of the Top Half of Kijanolide," Tetrahedron Lett. 1989, 30, 7309. 10.1016/S0040-4039(00)70684-8

70.   W. R. Roush, A. P. Essenfeld, J. S. Warmus, and B. B. Brown, "Synthesis and Diels-Alder Reactions of 2-Alkyl-5-methylene-1,3-dioxolan-4-ones and 2-Alkyl-3-acyl-5-methylene-1,3-oxazolidin-4-ones:  Highly Exo and Diastereoface Selective Chiral Ketene Equivalents," Tetrahedron Lett. 1989, 30, 7305. 10.1016/S0040-4039(00)70683-6

69.   W. R. Roush, L. Banfi, J. C. Park, and L. K. Hoong, "The Asymmetric Allylboration Reaction:  Dependence of Rate and Enantioselectivity on the Chiral Auxiliary," Tetrahedron Lett. 1989, 30, 6457. 10.1016/S0040-4039(01)88993-0 

68.   W. R. Roush and A. D. Palkowitz, "Synthesis of the C(1)-C(15) Segment of Streptovaricin D," J. Org. Chem. 1989, 54, 3009. 10.1021/jo00274a008

67.   W. R. Roush, M. R. Michaelides, D. F. Tai, B. M. Lesur, W. K. M. Chong, and D. J. Harris, "A Highly Stereoselective Synthesis of (+)-Olivin, the Aglycone of Olivomycin A," J. Am. Chem. Soc. 1989, 111, 2984. 10.1021/ja00190a036

66.   J. W. Coe and W. R. Roush, "Studies of an Intramolecular Diels-Alder Approach to the Nargenicins:  Involvement of Boat-Like Transition States in the Cyclizations of Substituted 1,7,9-Decatrien-3-ones," J. Org. Chem. 1989, 54, 915. 10.1021/jo00265a036

65.   W. R. Roush, "Applications of Allylboron Compounds in the Synthesis of Carbohydrates and Polyhydroxylated Natural Products," in "Trends in Synthetic Carbohydrate Chemistry," American Chemical Society Symposium Series Vol. 386; D. Horton, L. D. Hawkins, and G. McGarvey, eds.; ACS: Washington, 1989, p. 242.  

64.   W. R. Roush, "Evolution of a Strategy for the Synthesis of Olivomycin A:  Development of Methodology for the Diastereo- and Enantioselective Synthesis of Carbohydrates from Acyclic Precursors,"  in "Strategies & Tactics in Organic Synthesis," Vol. 2, Lindberg, T., ed.; Academic Press:  San Diego, 1989; p. 323. 

63.   W. R. Roush, K. A. Ando, D. B. Powers, R. L. Halterman, and A. D. Palkowitz, "Enantioselective Synthesis Using Diisopropyl Tartrate Modified (E)- and (Z)-Crotylboronates:  Reactions with Achiral Aldehydes," Tetrahedron Lett. 1988, 29, 5579. 10.1016/S0040-4039(00)80816-3

62.   W. R. Roush, B. B. Brown, and S. E. Drozda, "A Highly Stereoselective Synthesis of the Octahydronaphthalene Subunit of Kijanolide and Tetronolide," Tetrahedron Lett. 1988, 29, 3541.  10.1016/0040-4039(88)85287-0

61.   W. R. Roush and R. Riva, "Enantioselective Synthesis of the Bottom Half of Chlorothricolide.  2.  A Comparative Study of Substituent Effects on the Stereoselectivity of the Key Intramolecular Diels-Alder Reaction," J. Org. Chem. 1988, 53, 710.  10.1021/jo00238a049

60.   W. R. Roush and L. Banfi, "N,N'-Dibenzyl-N,N'-ethylene Tartramide, a Rationally Designed Chiral Auxiliary for the Allylboration Reaction," J. Am. Chem. Soc. 1988, 110, 3979. 10.1021/ja00220a041

59.   W. R. Roush, M. R. Michaelides, D. F. Tai, and W. K. M. Chong, "A Highly Stereoselective Total Synthesis of the Natural Enantiomer of Olivin," J. Am. Chem. Soc. 1987, 109, 7575. 10.1021/ja00258a077

58.   W. R. Roush, J. A. Straub, and R. J. Brown, "Stereochemistry of the Epoxidations of Acyclic Allylic Amides.  Applications Toward the Synthesis of 2,3,6-Trideoxy-3-aminohexoses," J. Org. Chem. 1987, 52, 5127. 10.1021/jo00232a014

57.   W. R. Roush, A. P. Essenfeld, and J. S. Warmus, "Effect of Dienophile Activating Group on the Stereoselectivity of the Intramolecular Diels-Alder Reaction," Tetrahedron Lett. 1987, 28, 2447. 10.1016/S0040-4039(00)95437-6

56.   W. R. Roush and J. W. Coe, "Studies on the Synthesis of Nargenicin A1.  An Example of an Intramolecular Diels-Alder Reaction that Proceeds with a Boat-Like Conformation of the Connecting Chain," Tetrahedron Lett. 1987, 28, 931. 10.1016/S0040-4039(00)95877-5

55.   W. R. Roush and A. D. Palkowitz, "Applications of Tartrate Ester Modified Allylic Boronates in Organic Synthesis:  An Efficient, Highly Stereoselective Synthesis of the C(19)-C(29) Segment of Rifamycin S," J. Am. Chem. Soc. 1987, 109, 953. 10.1021/ja00237a082

54.   W. R. Roush, A. D. Palkowitz, and M. A. J. Palmer, "Reactions of Diisopropyl Tartrate Modified Allyl, (E)- and (Z)-Crotylboronates with b-Alkoxy-a-methylpropionaldehydes:  A Reagent Based Solution to the Acyclic Dipropionate Problem," J. Org. Chem. 1987, 52, 316. 10.1021/jo00378a041

53.   R. L. Halterman, W. R. Roush, and L. K. Hoong, "Analytical Resolution of Secondary Methyl Ethers by Chiral Complexation Gas Chromatography," J. Org. Chem. 1987, 52, 1152. 10.1021/jo00382a036

52.   W. R. Roush and S. Russo-Rodriguez, "Trichothecene Degradation Studies.  3. Synthesis of 12,13-Deoxy-12,13-Methanoanguidine and 12-Epianguidine, Two Optically Active Analogues of the Epoxytricothecene Mycotoxin, Anguidine," J. Org. Chem. 1987, 52, 603. 10.1021/jo00380a022

51.   W. R. Roush and S. Russo-Rodriguez, "Trichothecene Degradation Studies.  2. Synthesis of 13-[14C]-Anguidine," J. Org. Chem. 1987, 52, 598. 10.1021/jo00380a021

50.   W. R. Roush and M. R. Michaelides, "Studies on the Total Synthesis of Sesbanimide:  A Highly Diastereoselective Synthesis of the AB Ring System," Tetrahedron Lett. 1986, 27, 3353. 10.1016/S0040-4039(00)84794-2

49.   W. R. Roush and J. A. Straub, "Total Synthesis of the AB Disaccharide Unit of Olivomycin A," Tetrahedron Lett. 1986, 27, 3349. 10.1016/S0040-4039(00)84793-0

48.   W. R. Roush, M. A. Adam, A. E. Walts, and D. J. Harris, "Stereochemistry of the Reactions of Substituted Allylboronates with Chiral Aldehydes.  Factors Influencing Aldehyde Diastereofacial Selectivity," J. Am. Chem. Soc. 1986, 108, 3422. 10.1021/ja00272a043

47.   W. R. Roush and R. L. Halterman, "Diisopropyl Tartrate Modified (E)-Crotylboronates:  Highly Enantioselective Propionate (E)-Enolate Equivalents," J. Am. Chem. Soc. 1986, 108, 294. 10.1021/ja00262a018

46.   W. R. Roush and S. Russo-Rodriguez, "Trichothecene Degradation Studies:  Synthesis of 12,13-Deoxyanguidine and 12,13-Deoxyverrucarol," J. Org. Chem. 1985, 50, 5465. 10.1021/jo00350a004

45.   W. R. Roush, M. A. Marletta, S. Russo-Rodriguez, and J. Recchia, "Trichothecene Metabolism Studies.  2. Structure of 3a-(1"b-D-Glucopyranosiduronyl)-8a-Isovaleryloxy-Scirpen-3,4b,15-Triol 15-Acetate Produced from T-2 Toxin In Vitro," Tetrahedron Lett. 1985, 26, 5231. 10.1016/S0040-4039(00)95002-0

44.   W. R. Roush, A. E. Walts, and L. K. Hoong, "Diastereo- and Enantioselective Aldehyde Addition Reactions of 2-Allyl-1,3,2-dioxaborolane-4,5-dicarboxylic Esters, A Useful Class of Tartrate Ester Modified Allylboronates," J. Am. Chem. Soc. 1985, 107, 8186. 10.1021/ja00312a062

43.   W. R. Roush and A. E. Walts, "Stereochemistry of the Reactions of Pinacol Allylboronate with Two a,b-Dialkoxyaldehydes," Tetrahedron Lett. 1985, 26, 3427. 10.1016/S0040-4039(00)98655-6

42.   W. R. Roush and M. A. Adam, "Directed Openings of 2,3-Epoxy Alcohols via Reactions with Isocyanates:  Synthesis of (+)-erythro-Dihydrosphingosine," J. Org. Chem. 1985, 50, 3752. 10.1021/jo00220a015

41.   W. R. Roush and S. Russo-Rodriguez, "Synthesis of 4b-Acetoxyscirpen-3a,15-diol," J. Org. Chem. 1985, 50, 3224. 10.1021/jo00217a046

40.   W. R. Roush and M. Kageyama, "Enantioselective Synthesis of the Bottom-Half of Chlorothricolide," Tetrahedron Lett. 1985, 26, 4327. 10.1016/S0040-4039(00)98725-2

39.   W. R. Roush, M. A. Adam, and D. J. Harris, "Stereochemistry of Crotylboronate Additions to a,b-Dialkoxy Aldehydes," J. Org. Chem. 1985, 50, 2000. 10.1021/jo00211a051

38.   A. E. Walts and W. R. Roush, "A Stereorational Total Synthesis of (-)-Ptilocaulin," Tetrahedron 1985, 41, 3463. 10.1016/S0040-4020(01)96701-8

37.   W. R. Roush, M. A. Marletta, S. Russo-Rodriguez, and J. Recchia, "Trichothecene Metabolism Studies:  Isolation and Structure Determination of 15-Acetyl-3a-(1'b-D-Glucopyranosiduronyl)-scirpen-3,4b,15-triol," J. Am. Chem. Soc. 1985, 107, 3354. 10.1021/ja00297a055

36.   W. R. Roush and S. M. Hagadorn, "Synthesis of Mycarose and Epi-Axenose from Non-Carbohydrate Precursors," Carbohydr. Res. 1985, 136, 187. 10.1016/0008-6215(85)85195-8

35.   W. R. Roush, S. M. Peseckis, and A. E. Walts, "Synthesis of X-14547A," J. Org. Chem. 1984, 49, 3429.

34.   W. R. Roush and T. A. Blizzard, "Synthesis of Verrucarin B," J. Org. Chem. 1984, 49, 4332. 10.1021/jo00197a002

33.   M. A. Blanchette, W. Choy, J. T. Davis, A. P. Essenfeld, S. Masamune, W. R. Roush, and T. Sakai, "Horner-Wadsworth-Emmons Reaction:  Use of Lithium Chloride and an Amine for Base-Sensitive Compounds," Tetrahedron Lett. 1984, 25, 2183. 10.1016/S0040-4039(01)80205-7

32.   W. R. Roush, H. R. Gillis, and A. P. Essenfeld, "Hydrofluoric Acid Catalyzed Intramolecular Diels-Alder Reactions," J. Org. Chem. 1984, 49, 4674. 10.1021/jo00198a018

31.   W. R. Roush and T. A. Blizzard, "Synthesis of Epoxytrichothecenes:  Verrucarin J and Verrucarin J Isomers," J. Org. Chem. 1984, 49, 1772. 10.1021/jo00184a021

30.   W. R. Roush and A. E. Walts, "Synthesis of (-)-Ptilocaulin," J. Am. Chem. Soc. 1984, 106, 721. 10.1021/ja00315a044

29.   W. R. Roush and A. P. Spada, "Synthesis of Trichoverrol B," Tetrahedron Lett. 1983, 24, 3693. 10.1016/S0040-4039(00)94511-8

28.   W. R. Roush and R. J. Brown, "Total Synthesis of Carbohydrates.  3. Efficient, Enantioselective Syntheses of 2,6-Dideoxyhexoses," J. Org. Chem. 1983, 48, 5093. 10.1021/jo00173a057

27.   W. R. Roush, R. J. Brown, and M. DiMare, "Total Synthesis of Carbohydrates.  2. Regiochemical Control of Nucleophilic Ring Opening of Acylated 2,3-Epoxy Alcohols," J. Org. Chem. 1983, 48, 5083. 10.1021/jo00173a056

26.   W. R. Roush and B. M. Lesur, "Stereochemistry of Vinyl Cuprate Additions to Carbohydrate-Derived Enones and a,b-Unsaturated Esters," Tetrahedron Lett. 1983, 24, 2231. 10.1016/S0040-4039(00)81891-2

25.   W. R. Roush, D. J. Harris, and B. M. Lesur, "Studies on the Synthesis of Olivin:  Diastereoselective Synthesis of a Functionalized D-Fucose Derivative," Tetrahedron Lett. 1983, 24, 2227. 10.1016/S0040-4039(00)81890-0

24.   W. R. Roush, M. A. Adam, and S. M. Peseckis, "Regioselectivity of the Reactions of Trialkylaluminum Reagents with 2,3-Epoxyalcohols:  Application to the Synthesis of a-Chiral Aldehydes," Tetrahedron Lett. 1983, 24, 1377. 10.1016/S0040-4039(00)81660-3

23.   W. R. Roush and T. E. D'Ambra, "Total Synthesis of (±)-Verrucarol," J. Am. Chem. Soc. 1983, 105, 1058. 10.1021/ja00342a071

22.   W. R. Roush and T. A. Blizzard, "Synthesis of Verrucarin J," J. Org. Chem. 1983, 48, 758. 10.1021/jo00153a035

21.   W. R. Roush and S. M. Peseckis, "Studies on the Total Synthesis of Antibiotic X-14547A:  The Pentaene Approach," Tetrahedron Lett. 1982, 23, 4879. 10.1016/S0040-4039(00)85737-8

20.   W. R. Roush and H. R. Gillis, "Further Stereochemical Aspects of Intramolecular Diels-Alder Reactions in the Undeca-2,8,10-trienoate Ester Series," J. Org. Chem. 1982, 47, 4825. 10.1021/jo00146a001

19.   W. R. Roush and A. P. Spada, "Enantio- and Stereoselective Syntheses of the Dihydroxyoctadienoic Acid Fragments of the Roridins and Trichoverrins,"  Tetrahedron Lett. 1982, 23, 3773. 10.1016/S0040-4039(00)87703-5

18.   S. E. Hall and W. R. Roush, "Total Synthesis of the Bottom-Half of Chlorothricolide," J. Org. Chem. 1982, 47, 4611. 10.1021/jo00145a002

17.   W. R. Roush, T. A. Blizzard, and F. Z. Basha, "Methodology for the Synthesis of the Acyclic Portions of Verrucarins A and J," Tetrahedron Lett. 1982, 23, 2331. 10.1016/S0040-4039(00)87334-7

16.   W. R. Roush, H. R. Gillis, and A. I. Ko, "Stereochemical Aspects of the Intramolecular Diels-Alder Reactions of Methyl Deca-2,7,9-trienoates.  3. Thermal, Lewis-Acid Catalyzed, and Asymmetric Cyclizations," J. Am. Chem. Soc. 1982, 104, 2269.  10.1021/ja00372a027

15.   W. R. Roush and R. J. Brown, "Total Synthesis of Carbohydrates: Stereoselective Syntheses of 2,6-Dideoxy-D-arabino-Hexose and 2,6-Dideoxy-D-ribo-Hexose," J. Org. Chem. 1982, 47, 1371. 10.1021/jo00346a050

14.   W. R. Roush and T. E. D'Ambra, "Synthesis of a Bicyclic Precursor to Verrucarol:  Application of a Trimethylsilyl-Controlled Diels-Alder Reaction and Wagner-Meerwein Rearrangement Sequence," J. Org. Chem. 1981, 46, 5045. 10.1021/jo00337a059

13.   W. R. Roush and S. M. Peseckis, "Intramolecular Diels-Alder Reactions:  The Angularly-Methylated Trans-Perhydroindane Ring System," J. Am. Chem. Soc. 1981, 103, 6696. 10.1021/ja00412a027  

12.   W. R. Roush and S. E. Hall, "Studies on the Total Synthesis of Chlorothricolide:  Stereochemical Aspects of the Intramolecular Diels-Alder Reactions of Methyl Undeca-2,8,10-trienoates," J. Am. Chem. Soc. 1981, 103, 5200. 10.1021/ja00407a042

11.   W. R. Roush and A. G. Myers, "Antibiotic X-14547A:  Total Synthesis of the Right-Hand Half," J. Org. Chem. 1981, 46, 1509. 10.1021/jo00320a060

10.   M. Fieser, R. L. Danheiser, and W. R. Roush, "Reagents for Organic Synthesis," Volume 9, Wiley-Interscience:  New York, 1981.

  9.   W. R. Roush and H. R. Gillis, "An Improved Synthesis of the Perhyroindenone Precursor of Dendrobine," J. Org. Chem. 1980, 45, 4283. 10.1021/jo01310a006

  8.   W. R. Roush and H. R. Gillis, "Stereochemical Aspects of the Intramolecular Diels-Alder Reactions of Methyl Deca-2,7,9-trienoates.  2.  Lewis Acid Catalysis," J. Org. Chem. 1980, 45, 4267. 10.1021/jo01309a055

  7.   W. R. Roush, A. I. Ko, and H. R. Gillis, "Stereochemical Aspects of the Intramolecular Diels-Alder Reactions of Methyl Deca-2,7,9-trienoates.  1. Thermal Cyclizations," J. Org. Chem. 1980, 45, 4264. 10.1021/jo01309a054

  6.   W. R. Roush and T. E. D'Ambra, "Studies on the Total Synthesis of Verrucarol:  A Stereoselective Synthesis of 13,14-Dinor-15-hydroxytrichothecene," J. Org. Chem. 1980, 45, 3927. 10.1021/jo01307a045

  5.   W. R. Roush, H. R. Gillis, and S. E. Hall, "Stereoselective Synthesis of Substituted Methyl (Z,E,E)-Deca-2,7,9-trienoates and Substituted Methyl (Z,E,E)-Undeca-2,8,10-trienoates," Tetrahedron Lett. 1980, 1023. 10.1016/S0040-4039(00)78829-0

  4.   W. R. Roush, "Total Synthesis of (±)-Dendrobine," J. Am. Chem. Soc. 1980, 102, 1390. 10.1021/ja00524a027

  3.   W. R. Roush, "Stereochemical Aspects of the Intramolecular Diels-Alder Reactions of Methyl (E,E,E)- and (Z,E,E)-6-Alkoxy-11-methyldodeca-2,7,9-trienoate," J. Org. Chem. 1979, 44, 4008. 10.1021/jo01336a067

  2.   W. R. Roush, "Total Synthesis of (±)-Dendrobine," J. Am. Chem. Soc. 1978, 100, 3599. 10.1021/ja00479a053

 1.   W. R. Roush, D. Feitler and J. Rebek, "Polymer-Bound Tosyl Azide," Tetrahedron Lett. 1974, 1391. 10.1016/S0040-4039(01)82499-0