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166. Toriyama, F.; Cornella, J.; Wimmer, L.; Chen, T.-G.; Dixon, D. D.; Creech, G.; Baran, P. S. Redox-Active Esters in Fe-catalyzed C-C Coupling, J. Am. Chem. Soc. 2016, ASAP. [Supporting Information]
 
165. Cernijenko, A.; Risgaard, R.; Baran, P. S. 11-Step Total Synthesis of (-)-Maoecrystal V, J. Am. Chem. Soc. 2016, ASAP. [Supporting Information]
 
164. Wang, J.; Qin, T.; Chen, T.-E.; Wimmer, L.; Edwards, J. T.; Cornella, J.; Vokits, B.; Shaw, S. A.; Baran, P. S. Nickel-Catalyzed Cross-Coupling of Redox-Active Esters with Boronic Acids, Angew. Chem. Int. Ed. 2016, 55, ASAP. [Supporting Information]
 
163. Martinez, L. P.; Umemiya, S.; Wengryniuk, S. E.; Baran, P. S. 11-Step Total Synthesis of Pallambins C and D, J. Am. Chem. Soc. 2016, ASAP. [Supporting Information]
 
162. Yuan, C.; Jin, Y.; Wilde, N. C.; Baran, P. S. Short, Enantioselective Total Synthesis of Highly Oxidized Taxanes, Angew. Chem. Int. Ed., 2016, ASAP. [Supporting Information]
 
161. Horn, E. J.; Rosen, B. R.; Baran, P. S. Synthetic Organic Electrochemistry: An Enabling and Innately Sustainable Method, ACS Cent. Sci., 2016, 2, 302-308.
 
160. Qin, T.; Cornella, J.; Li, C.; Malins, L. R.; Edwards, J. T.; Kawamura, S.; Maxwell, B. D.; Eastgate, M. D.; Baran, P. S. A General Alkyl-Alkyl Cross-Coupling Enabled by Redox-Active Esters and Alkylzinc Reagents, Science, 2016, 352, 801-805. [Supporting Information]
 
159. Horn, E. J.; Rosen, B. R.; Chen, Y.; Tang, J.; Chen, K.; Eastgate, M. D.; Baran, P. S. Scalable and sustainable electrochemical allylic C-H oxidation, Nature, 2016, 533, 78-81. [Supporting Information]
 
158. Kawamura, S.; Chu, H.; Felding, J.; Baran, P. S. Nineteen-step total synthesis of (+)-phorbol, Nature, 2016, 532, 90-93. [Supporting Information]
 
157. Cornella, J.; Edwards, J. T.; Qin, T.; Kawamura, S.; Wang, J. Pan, C-M.; Gianatassio, R.; Schmidt, M. A.; Eastgate, M. D.; Baran, P. S. Practical Ni-Catalyzed Aryl-Alkyl Cross-Coupling of Secondary Redox-Active Esters, J. Am. Chem. Soc., 2016, 138 (7), pp 2174-2177. [Supporting Information]
 
156. Gianatassio, R.; Lopchuk, J. M.; Wang, J.; Pan, C-M.; Malins, L. R.; Prieto, L.; Brandt, T. A.; Collins, M. R.; Gallego, G. M.; Sach, N. W.; Spangler, J. E.; Zhu, H.; Baran, P. S. Strain-release amination, Science, 2016, 351, pp. 241-246. [Supporting Information]
 
155. Villaume, M.T.; Sella, E.; Saul, G.; Borzilleri, R. M.; Fargnoli, J.; Johnston, K. A.; Zhang, H.; Fereshteh, M. P.; Dhar, T. G. M.; Baran, P. S. Antroquinonol A: Scalable Synthesis and Preclinical Biology of a Phase 2 Drug Candidate, ACS Cent. Sci., 2016, 2 (1), pp 27-31. [Supporting Information]
 
154. See, Y. Y.; Herrmann, A. T.; Aihara, Y.; Baran, P. S. Scalable C-H Oxidation with Copper: Synthesis of Polyoxypregnanes, J. Am. Chem. Soc, 2015, 137, 13776-13779. [Supporting Information]
153. Jin, Y.; Yeh, C.-H.; Kuttruff, C. A.; Jorgensen, L.; Dunstl, G.; Felding, J.; Natarajan, S. R.; Baran, P. S. C-H Oxidation of Ingenanes Enables Potent and Selective Protein Kinase C Isoform Activation, Angew. Chem. Int. Ed., 2015, 54, 14044-14048. [Supporting Information]
 
152. Feng, Y.; Holte, D.; Zoller, J.; Umemiya, S.; Simke, L. R.; Baran, P. S. Total Synthesis of Verruculogen and Fumitremorgin A Enabled by Ligand-Controlled C-H Borylation, J. Am. Chem. Soc, 137, 10160-10163. [Supporting Information]
 
151. Dao, H. T.; Li, C.; Michaudel, Q.; Maxwell, B. D.; Baran, P. S. Hydromethylation of Unactivated Olefins, J. Am. Chem. Soc, 2015, 137, 8046-8049. [Supporting Information]
 
150. Gui, J.; Pan, C-M.; Jin, Y.; Qin, T.; Lo, J. C.; Lee, B. J.; Spergel, S. H.; Mertzman, M. E.; Pitts, W. J.; La Cruz, T. E.; Schmidt, M. A.; Darvatkar, N.; Natarajan, S. R.; Baran, P. S. Practical Olefin Hydroamination with nitroarenes, Science 2015, 348, 886–891. [Supporting Information]
 
149. Michaudel, Q.; Ishihara, Y.; Baran, P. S. Academia–Industry Symbiosis in Organic Chemistry, Acc. Chem. Res. 2015, 48, 712–721.
 
148. Renata, H.; Zhou, Q.; Dünstl, G.; Felding, J.; Merchant, R. R.; Yeh, C.-H.; Baran, P. S. Development of a Concise Synthesis of Ouabagenin and Hydroxylated Corticosteroid Analogues, J. Am. Chem. Soc. 2015, 137,1330–1340. [Supporting Information]
 
147. Lo, J. C.; Gui, J.; Yabe, Y.; Pan, C. -M.; Baran, P. S. Functionalized Olefin Cross-Coupling to Construct Carbon-Carbon Bonds, Nature 2014, 343–348. [Supporting Information]
 
146. Maimone, T. J.; Ishihara, Y.; Baran, P. S. Scalable Total Syntheses of (−)-Hapalindole U and (+)-Ambiguine H, Tetrahedron 2015, 71, 3652–3665.
 
145. Dao, H. T.; Baran, P. S. Quinone Diazides for Olefin Functionalization, Angew. Chem. Int. Ed. 2014, 14382–14386. [Supporting Information]
 
144. Rodriguez, R. A.; Barrios Steed, D.; Kawamata, Y.; Su, S.; Smith, P. A.; Steed, T. C.; Romesberg, F. E.; Baran, P. S. Axinellamines as Broad-Spectrum Antibacterial Agents: Scalable Synthesis and Biology, J. Am. Chem. Soc. 2014, 136, 15403-15413. [Supporting Information]
 
143. Michaudel, Q.; Journot, G.; Regueiro-Ren, A.; Goswami, A.; Guo, Z., Tully, T. P., Zou, L., Ramabhadran, R. O., Houk, K. N., Baran, P. S. Improving Physical Properties via C–H Oxidation: Chemical and Enzymatic Approaches, Angew. Chem. Int. Ed. 2014, 53, 12091-12096. [Supporting Information]
 
142. O'Brien, A. G.; Maruyama, A.; Inokuma, Y.; Fujita, M.; Baran, P. S.; Blackmond, D. G. Radical C–H Functionalization of Heteroarenes under Electrochemical Control, Angew. Chem. Int. Ed. 2014, 53, 11868-11871. [Supporting Information]
 
141. Cherney, E. C.; Lopchuk, J. M.; Green, J. C.; Baran, P. S. A Unified Approach to ent-Atisane Diterpenes and Related Alkaloids: Synthesis of (–)-Methyl Atisenoate, (–)-Isoatisine, and the Hetidine Skeleton, J. Am. Chem. Soc. 2014, 136, 12592-12595. [Supporting Information]
 
140. Gianatassio, R.; Kawamura, S.; Eprile, C. L.; Foo, K.; Ge, J.; Burns, A. C.; Collins, M. R.;Baran, P. S. Simple Sulfinate Synthesis Enables C-H Trifluoromethylcyclopropanation, Angew. Chem. Int. Ed. 2014, 53, 9851-9855. [Supporting Information]
 
139. Rodriguez, R. A.; Pan, C. -M.; Yabe, Y.; Kawamata, Y.; Eastgate, M. D.; Baran, P. S. Palau'chlor: A Practical and Reactive Chlorinating Reagent J. Am. Chem. Soc. 2014, 136, 6908-6911. [Supporting Information]
 
138. Rosen, B. R.; Werner, E. W.; O'Brien, A. G.; Baran, P. S. Total Synthesis of Dixiamycin B by Electrochemical Oxidation J. Am. Chem. Soc. 2014, 136, 5571-5574. [Supporting Information]
 
137. McKerrall, S. J.; Jorgensen, L.; Kuttruff, C. A.; Ungeheuer, F.; Baran, P. S. Development of a Concise Synthesis of (+)-Ingenol J. Am. Chem. Soc. 2014, 136, 5799-5810. [Supporting Information]
 
136. Foo, K.; Sella, E.; Thome, I.; Eastgate, M. D.; Baran, P. S. A Mild, Ferrocene-catalyzed C-H Imidation of (Hetero)Arenes J. Am. Chem. Soc. 2014, 136, 5279-5282. [Supporting Information]
 
135. Wilde, N. C.; Isomura, M.; Mendoza, A.; Baran, P. S. Two-Phase Synthesis of (–)-Taxuyunnanine D. J. Am. Chem. Soc. 2014, 136, 4909-4912. [Supporting Information]
 
134. Gui, J.; Zhou, Q.; Pan, C.-M.; Yabe, Y.; Burns, A. C.; Collins, M. R.; Ornelas, M. A.; Ishihara, Y.; Baran, P. S. A C–H Methylation Reaction of Heteroarenes Inspired by Radical SAM Methyl Transferase. J. Am. Chem. Soc. 2014, 136, 4853-4856. [Supporting Information]
 
133. Gutekunst, W. R.; Baran, P. S. Applications of C–H Functionalization Logic to Cyclobutane Synthesis. J. Org. Chem. 2014, 79, 2430-2452. [Supporting Information]
 
132. O’Hara, F.; Burns, A. C.; Collins, M. R.; Dalvie, D.; Ornelas, M. A.; Vaz, A. D. N.; Fujiwara, Y.; Baran, P. S. A Simple Litmus Test for Aldehyde Oxidase Metabolism of Heteroarenes. J. Med. Chem. 2014, 57, 1616-1620.[Supporting Information]
 
131. Lo, J. C. ; Yabe, Y.; Baran, P.S. A Practical and Catalytic Reductive Olefin Coupling, J. Am. Chem. Soc. 2014, 136, 1304-1307. [Supporting Information]
 
130. Kuttruff, C. A.; Eastgate, M. D.; Baran, P.S. Natural Product Synthesis in the Age of Scalability, Nat. Prod. Rep. 2014, 31, 419-432.
 
129. Teufel, R.; Miyanaga, A. ; Michaudel, Q.; Stull, F.; Louie, G.; Noel, J. K.; Baran, P.S.; Palfey, B.; Moore, B. S. Flavin-Mediated Dual Oxidation Controls an Enzymatic Favorskii-type Rearrangement, Nature 2013, 503, 552-556.[Supporting Information]
 
128. Zhou, Q.; Gui, J.; Pan, C.-M.; Albone, E.; Cheng, X.; Suh, E.M.; Grasso, L.; Ishihara, Y.; Baran, P.S. Bioconjugation by Native Chemical Tagging of C–H Bonds, J. Am. Chem. Soc. 2013, 135, 12994-12997. [Supporting Information]
 
127. Jørgensen, L.; McKerrall, S.J.; Kuttruff, C.A.; Ungeheuer, F.; Felding, J.; Baran, P.S. 14-Step Synthesis of (+)-Ingenol from (+)-3-Carene, Science 2013, 341, 878-882. [Supporting Information]
 
126. O'Hara, F.; Blackmond, D.G.; Baran, P.S. Radical-Based Regioselective C–H Functionalization of Electron-Deficient Heteroarenes: Scope, Tunability, and Predictability, J. Am. Chem. Soc. 2013, 135, 12122-12134. [Supporting information]
 
125. Cherney, E.C.; Green, J.C.; Baran, P.S. Synthesis of ent-Kaurane and Beyerane Diterpenoids by Controlled Fragmentations of Overbred Intermediates, Angew. Chem. Int. Ed. 2013, 52, 9019-9022. [Supporting information]
 
124. Rosen, B.R.; Simke, L.R.; Thuy-Boun, P.S.; Dixon, D.D.; Yu, J.-Q.; Baran, P.S. C–H Functionalization Logic Enables Synthesis of (+)-Hongoquercin A and Related Compounds, Angew. Chem. Int. Ed. 2013, 52, 7317–7320. [Supporting information]
 
123. O'Hara, F.; Baxter, R.D.; O'Brien, A.G.; Collins, M.R.; Dixon, J.A.; Fujiwara, Y.; Ishihara, Y.; Baran, P.S. Preparation and Purification of Zinc Sulfinate Reagents for Drug Discovery, Nature Protocols 2013, 8, 1042-1047. [Supporting information]
 
122. Ishihara, Y.; Mendoza, A.; Baran, P.S. Total Synthesis of Taxane Terpenes: Cyclase Phase, Tetrahedron 2013, 69, 5685-5701.
 
121. Usui, I.; Lin, D.W.; Masuda, T.; Baran, P.S. Convergent Synthesis and Structural Confirmation of Phellodonin and Sarcodonin ε, Org Lett. 2013, 15, 2080-2083. [Supporting information]
 
120. Zhou, Q.; Ruffoni, A.; Gianatassio, R.; Fujiwara, Y.; Sella, E.; Shabat, D. ; Baran, P.S. Direct Synthesis of Fluorinated Heteroarylether Bioisosteres, Angew. Chem. Int. Ed. 2013, 52, 3949-3952. [Supporting information]
 
119. Wengryniuk, S.E.; Weickgenannt, A.; Reiher, C.; Strotman, N.A.; Chen, K.; Eastgate, M.D. ; Baran, P.S. Regioselective Bromination of Fused Heterocyclic N-Oxides, Org. Lett. 2013, 15, 792-795. [Supporting information]
 
118. Renata, H.; Zhou, Q.; Baran, P.S. Strategic Redox Relay Enables A Scalable Synthesis of Ouabagenin, A Bioactive Cardenolide, Science 2013, 339, 59-63. [Supporting information]
 
117. Mendoza, A.; Baran, P.S. Synthesis: A Constructive Debate - Practical Chemistry, Nature 2012, 492, 188-189.
 
116. Fujiwara, Y.; Dixon, J.A.; O'Hara, F.; Daa Funder, E.; Dixon, D.D.; Rodriguez, R.A.; Baxter, R.D.; Herlé, B.; Sach, N.; Collins, M.R.; Ishihara, Y.; Baran, P.S. Practical and Innate Carbon–Hydrogen Functionalization of Heterocycles, Nature 2012, 492, 95-100. [Supporting information]
 
115. Foo, K.; Usui, I.; Gotz, D.C.G. Werner, E.W.; Holte, D.; Baran, P.S. Scalable, Enantioselective Synthesis of Germacrenes and Related Sesquiterpenes Inspiried by Terpene Cyclase Phase Logic, Angew. Chem. Int. Ed. 2012, 51, 11491-11495. [Supporting information]
 
114. Voica, A.F.; Mendoza, A.; Gutekunst, W.R.; Fraga, J.O.; Baran, P.S. Guided Desaturation of Unactivated Aliphatics, Nature Chem. 2012, 4, 629-635. [Supporting information]
 
113. Gutekunst, W.R.; Gianatassio, R.; Baran, P.S. Sequential Csp3–H Arylation and Olefination: Total Synthesis of the Proposed Structure of Pipercyclobutanamide A, Angew. Chem. Int. Ed. 2012, 51, 7507-7512. [Supporting information]
 
112. Dixon, D.D.; Lockner, J.W.; Zhou, Q.; Baran, P.S. Scalable, Divergent Synthesis of Meroterpenoids via "Borono-sclareolide", J. Am. Chem. Soc. 2012, 134, 8432-8435. [Supporting information]
 
111. Michaudel, Q.; Thevenet, D.; Baran, P.S. Intermolecular Ritter-Type C–H Amination of Unactivated sp3 Carbons, J. Am. Chem. Soc. 2012, 134, 2547-2550. [Supporting information]
 
110. Fujiwara, Y.; Dixon, J.A.; Rodriguez, R.A.; Baxter, R.D.; Dixon, D.D.; Collins, M.R.; Blackmond, D.G.; Baran, P.S. A New Reagent for Direct Difluoromethylation, J. Am. Chem. Soc. 2012, 134, 1494-1497. [Supporting Information]
109. Holte, D.; Gotz, D.C.G.; Baran, P.S. An Approach to Mimicking the Sesquiterpene Cyclase Phase by Nickel-Promoted Diene/Alkyne Cooligomerization, J. Org. Chem. 2012, 77, 825-842. [Supporting Information]
 
108. Mendoza, A.; Ishihara, Y.; Baran, P.S. Scalable EnantioselectiveTotal Synthesis of Taxanes, Nature Chem. 2012, 4, 21-25. [Supporting Information]
 
107. Gutekunst, W.R.; Baran, P.S. Total Synthesis and Structural Revision of the Piperarborenines via Sequential Cyclobutane C–H Arylation, J. Am. Chem. Soc. 2011, 133, 19076-19079. [Supporting Information]
 
106. Brueckl, T.; Baxter, R.D.; Ishihara, Y.; Baran, P.S. Innate and Guided C–H Functionalization Logic, Acc. Chem. Res. 2012, 45, 826-839.
 
105. Lockner, J.W.; Dixon, D.D.; Risgaard, R.; Baran, P.S. Practical Radical Cyclizations with Arylboronic Acids and Trifluoroborates, Org. Lett., 2011, 13, 5628-5631. [Supporting Information]
 
104. Seiple, I.B.; Su, S.; Young, I.S.; Nakamura, A.; Yamaguchi, J.; Jørgensen, L.; Rodriguez, R.A.; O'Malley, D.P.; Gaich, T.; Köck, M.; Baran, P.S. Enantioselective Total Syntheses of (–)-Palau'amine, (–)-Axinellamines, and (–)-Massadines, J. Am. Chem. Soc., 2011, 133, 14710-14726. [Supporting Information]
 
103. Su, S.; Rodriguez, R.A.; Baran, P.S. Scalable, Stereocontrolled Total Synthesis of (±)-Axinellamines A and B, J. Am. Chem. Soc., 2011, 133, 13922-13925. [Supporting Information]
 
102. Ji, Y.; Brueckl, T.; Baxter, R.D.; Fujiwara, Y.; Seiple, I.B.; Su, S.; Blackmond, D.G.; Baran, P.S. Innate C–H Trifluoromethylation of Heterocycles, PNAS, 108, 14411-14415. [Supporting Information]
 
101. Shi, J.; Manolikakes, G.; Yeh, C-H.; Guerrero, C.A.; Shenvi, R.A.; Shigehisa, H.; Baran, P.S. Scalable Synthesis of Cortistatin A and Related Structures, J. Am. Chem. Soc., 2011, 133, 8014-8027. [Supporting Information]
 
100. Fujiwara, Y.; Domingo, V.; Seiple, I.B.; Gianatassio, R.; Del Bel, M.; Baran, P.S. Practical C–H Functionalization of Quinones with Boronic Acids, J. Am. Chem. Soc., 2011, 133, 3292-3295. [Supporting Information]
 
99. Newhouse, T.R.; Baran, P.S. If C–H Bonds Could Talk – Selective C–H Bond Oxidation, Angew. Chem. Int. Ed., 2011, 50, 3362-3374.
 
98. Foo, K.; Newhouse, T.R.; Mori, I.; Takayama, H.; Baran, P.S. Total Synthesis-Guided Structure Elucidation of (+)-Psychotetramine, Angew. Chem. Int. Ed., 2011, 2716-2719. [Supporting Information]
 
97. Cherney, E.; Baran, P.S. Terpenoid-Alkaloids: Their Biosynthetic Twist of Fate and Total Synthesis, Isr. J. Chem. 2011, 51, 391-405.
 
96. Gutekunst, W.R.; Baran, P.S. C–H Functionalization Logic in Total Synthesis, Chem. Soc. Rev. 2011, 40, 1976-1991.
 
95. Jessing, M.; Baran, P.S. Oxidative Coupiing of Indoles with 3-Oxindoles, Heterocycles, 2011, 82, 1739-1745. Special issue dedicated to Professor Dr. Albert Eschenmoser on the Occasion of his 85th birthday.
 
94. Lin, D.W.; Masuda, T.; Biskup, M.B.; Nelson, J.D.; Baran, P.S. Synthesis-Guided Structural Revision of the Sarcodonin, Sarcoviolin, and Hydnellin Natural Product Family, J. Org. Chem. 2011, 76, 1013-1030. [Supporting Information]
 
93. Seiple, I.B.; Su, S.; Rodriguez, R.A.; Gianatassio, R.; Fujiwara, Y.; Sobel, A.L.; Baran, P.S. Direct C–H Arylation of Electron-Deficient Heterocycles with Arylboronic Acids, J. Am. Chem. Soc. 2010, 132, 13194-13196. [Supporting Information]
 
92. Ishihara, Y.; Baran, P.S. Two-Phase Terpene Total Synthesis: Historical Perspective and Application to the Taxol® Problem, Synlett, 2010, 12, 1733-1745.
 
91. Gaich, T.; Baran, P.S. Aiming for the Ideal Synthesis, J. Org. Chem. 2010, 75, 4657-4673.
 
90. Newhouse, T.; Lewis, C.A.; Eastman, K.J.; Baran, P.S. Scalable Total Syntheses of N–Linked Tryptamine Dimers by Direct Indole-Aniline Coupling: Psychotrimine and Kapakahines B and F, J. Am. Chem Soc. 2010, 132, 7119-7137. [Supporting Information]
 

89. Chen, K.; Ishihara, Y.; Gálan, M.M.; Baran, P.S. Total Synthesis of Eudesmane Terpenes: Cyclase Phase, Tetrahedron, 2010, 66, 4738-4744.

 

 
88. Seiple, I.B.; Su, S.; Young, I.S.; Lewis, C.A.; Yamaguchi, J.; Baran, P.S. Total Synthesis of Palau'amine, Angew. Chem. Int. Ed. 2010, 49, 1095-1098. [Supporting Information]
 
87. Chen, K.; Eschenmoser, A.; Baran, P.S. Strain Release in C–H Bond Activation?, Angew. Chem. Int. Ed. 2009, 48, 9705-9708. [Supporting Information]
 
86. Maimone, T.J.; Shi, J.; Ashida, S.; Baran, P.S. Total Synthesis of Vinigrol, J. Am. Chem. Soc. 2009, 131, 17066-17067. [Supporting Information]

 
85. Krawczuk, P.J.; Schöne, N.; Baran, P.S. A Synthesis of the Carbon Skeleton of Maoecrystal V, Org. Lett. 2009, 11, 4474-4476. [Supporting Information]
 
84. Luzung, M.R.; Lewis, C.A.; Baran, P.S. Direct, Chemoselective N-tert-Prenylation of Indoles by C–H Functionalization, Angew. Chem. Int. Ed. 2009, 48, 7025-7029. [Supporting Information]


 

83. Newhouse, T.; Baran, P.S.; Hoffmann, R.W. The Economies of Synthesis, Chem. Soc. Rev. 2009, 39, 3010-3021.


82. Burns, N.Z.; Krylova, I.N.; Hannoush, R.N.; Baran, P.S. Scalable Total Synthesis and Biological Evaluation of Haouamine A and Its Atropisomer, J. Am. Chem. Soc. 2009, 131, 9172-9173. [Supporting Information]

81. Chen, K.; Baran, P.S. Total synthesis of eudesmane terpenes by site-selective C–H oxidations, Nature, 2009, 459, 824-828.
[Supporting Information]

 
80. Young, I.S.; Baran, P.S. Protecting-group-free synthesis as an opportunity for invention, Nature Chemistry, 2009, 1, 193-205.

 
79. Shi, J; Shigehisa, H; Guerrero, C.A.; Shenvi, R.A.; Li, C.; Baran, P.S. Stereodivergent Synthesis of 17- and 17--ryl Steroids: Application and Biological Evaluation of D-Ring Cortistatin Analogues, Angew. Chem. Int. Ed., 2009, 48, 4328-4331. [Supporting Information]

 

78. Newhouse, T.; Lewis, C.A.; Baran, P.S. Enantiospecific Total Syntheses of Kapakahines B and F, J. Am. Chem. Soc., 2009, 131, 6360-6361.
[Supporting Information]


 
77. Burns, N.Z.; Baran, P.S.; Hoffmann, R.W. Redox Economy in Organic Synthesis, Angew. Chem. Int. Ed., 2009, 48, 2854-2867.

 
76. Shenvi, R.A.; O'Malley, D.P.; Baran, P.S. Chemoselectivity: The Mother of Invention in Total Synthesis, Acc. Chem. Res., 2009, 42, 530-541.
 
75. Burns, N.Z.; Jessing, M.; Baran, P.S. Total Syntheis of Haouamine A: the Indeno-Tetrahydropyridine Core, Tetrahedron, 2009, 65, 6600-6610.


 
74. Hafensteiner, B.D; Escribano, M.; Petricci, E.; Baran, P.S. An Improved Synthesis of alpha,beta-Unsaturated Nitrones Relavant to the Stephacidins and Analogs Therof, Bioorg. Med. Chem. Lett., 2009, 19, 3808-3810.
 
73. Eastman, K.; Baran, P.S. A Simple Method for the Direct Arylation of Indoles , Tetrahedron, 2009, 65, 3149-3154.


 
72. Richter, J.M.; Ishihara, Y.; Masuda, T.; Whitefield, B.W.; Llamas, T.; Pohjakallio, A.; Baran, P.S. Enantiospecific Total Synthesis of the Hapalindoles, Fischerindoles, and Welwitindolinones via a Redox Economic Approach, J. Am. Chem. Soc. 2008, 17938-17954. [Supporting Information]

 
71. Su, S.; Seiple, I.B.; Young, I.S.; Baran, P.S. Total Syntheses of (±)-Massadine and Massadine Chloride, J. Am. Chem. Soc. 2008, 130, 16490-16491. [Supporting Information]

 
70. DeMartino M. P.; Chen, K.; Baran, P.S. Intermolecular Enolate Heterocoupling: Scope, Mechanism, and Application, J. Am. Chem. Soc. 2008, 130, 11546-11560. [Supporting Information]

 


 
68. Chen, K.; Richter, J. M.; Baran, P.S. 1,3-Diol Synthesis via Controlled, Radical-Mediated C−H Functionalization, J. Am. Chem. Soc. 2008, 130, 7247-7249. [Supporting Information]



 
67. Shenvi, R.A.; Guerrero, C. A.; Shi, J.; Li, C.-C.; Baran, P.S. Synthesis of (+)-Cortistatin A, J. Am. Chem. Soc. 2008, 130, 7241-7243. [Supporting Information]


 
66. O'Malley, D.P.; Yamaguchi, J.; Young, I.S.; Seiple, I.B.; Baran, P.S. Total Synthesis of (±)-Axinellamines A and B, Angew. Chem. Int. Ed. 2008, 47, 3581-3583. [Supporting Information]




 
65. Yamaguchi, J.; Seiple, I.B.; Young, I.S.; O'Malley, D.P.; Maue, M.; Baran, P.S. Synthesis of 1,9-Dideoxy-pre-axinellamine, Angew. Chem. Int. Ed. 2008, 47, 3578-3580. [Supporting Information]




 
64. Maimone, T. J.; Voica, A.F.; Baran, P. S. A Concise Approach to Vinigrol, Angew. Chem. Int. Ed. 2008, 47, 3054-3056. [Supporting Information]




 
63. Burns, N.Z.; Baran, P.S. On the Origin of the Haouamine Alkaloids, Angew. Chem. Int. Ed. 2008, 47, 205-208. [Supporting Information]



 
62. Richter, J. M.; Whitefield, B.; Maimone, T. J.; Lin, D. W.; Castroviejo, P.; Baran, P. S. Scope and Mechanism of the Direct Indole Coupling Adjacent to Carbonyl Compounds: Total Synthesis of Acremoauxin A and Oxazinin 3, J. Am. Chem. Soc. 2007, 129, 12857-12869. [Supporting Information]




 
61. Grube, A.; Immel, S.; Baran, P. S.; Köck, M. Massadine Chloride: a Biosynthetic Precursor of Massadine and Stylissadine, Angew. Chem. Int. Ed. 2007, 46, 6721-6724.


 
60. Köck, M.; Grube, A.; Seiple, I.; Baran, P. S. The Pursuit of Palau’amine, Angew. Chem. Int. Ed. 2007, 46, 6586-6594.


 
59. Maimone, T. J.; Baran, P. S. Modern Synthetic Approaches to Terpenes, Nature Chem. Bio. 2007, 3, 396-407.

 

58. O'Malley, D. P.; Li, K.; Maue, M.; Zografos, A. L.; Baran, P. S. Total Synthesis of Dimeric Pyrrole-Imidazole Alkaloids: Sceptrin, Ageliferin, Nagelamide E, Oxysceptrin, Nakamuric Acid, and the Axinellamine Carbon Skelton, J. Am. Chem. Soc. 2007, 129, 4762-4775. [Supporting Information]



 

57. Baran, P.S.;Maimone, T. J.; Richter, J. M. Total synthesis of marine natural products without using protecting groups, Nature, 2007, 446, 404-408. [Supporting Inoformation]


 
56. Baran, P. S.; Shenvi, R. A. Total Synthesis of (±)–Chartelline C, J. Am. Chem. Soc. 2006, 128, 14028-14029. [Supporting Information]


 
55. Baran, P. S.; DeMartino, M. P. Intermolecular Enolate Heterocoupling, Angew. Chem. Int. Ed. 2006, 45, 7083-7086. [Supporting Information]


 

54. Baran, P.S.; Hafensteiner, B.D.; Ambhaikar, N. B.; Guerrero, C. A.; Gallagher, J. D. Enantioselective Total Synthesis of Avrainvillamide and the Stephacidins. J. Am. Chem. Soc. 2006, 128, 8678-8693. [Supporting Information]

 

53. Northrop, B.H.; O'Malley, D.P.; Zografos A. L.; Baran, P.S.; Houk, K. N. Mechanism of the Vinylcyclobutane Rearrangement of Sceptrin to Ageliferin and Nagelamide E. Angew. Chem. Int. Ed. 2006, 45, 4126-4130.

 
52. Baran, P. S.; Burns, N. Z. Total Synthesis of (±)-Haouamine A. J. Am. Chem. Soc.; 2006; 128; 3908-3909. [Supporting Information]

 
51. Baran, P. S.; Li, K; O'Malley, D.P.; Mitsos, C. Short, Enantioselective Total Synthesis of Sceptrin and Ageliferin by Programmed Oxaquadricyclane Fragmentation. Angew. Chem. Int. Ed. 2006, 45, 249-252. [Supporting Information]

 

 
50. Baran, P. S.; Shenvi, R. A.; Nguyen, S. A. One-Step Synthesis of 4,5-Disubstituted Pyrimidines Using Commercially Available and Inexpensive Reagents. Heterocycles 2006, 70, 581-586. Special issue dedicated to Professor Steve Weinreb.


 
49. Baran, P. S.; Richter, J. M. Enantioselective Total Syntheses of Welwitindolinone A and Fischerindoles I and G, J. Am. Chem. Soc.; 2005; 127(44); 15394-15396.
[Supporting Information]
 
48. Baran, P. S.; Guerrero, C.A.; Hafensteiner, B.D.; Ambhaikar, N.B. Total synthesis of Avrainvillamide (CJ-17,665) and Stephacidin B, Angew. Chem. Int. Ed. 2005, 44, 3892-3895. [Supporting Information 744KB]
 
47. Baran, P. S.; Shenvi, R.A.; Mitsos, C.A. A Remarkable Ring Contraction En Route to the Chartelline Alkaloids, Angew. Chem. Int. Ed. 2005, 44, 3714-3717. [Supporting Information 716KB]
 
 
45. Baran, P.S.; Richter, J.M.; Lin, D.W. Direct Coupling of Pyrroles with Carbonyl Compounds: Short, Enantioselective Synthesis of (S)-Ketorolac, Angew. Chem. Int. Ed. 2005, 44, 609-612. [Supporting Information 1.2MB]
 
44. Baran, P.S.; Richter, J.M. Direct Coupling of Indoles with Carbonyl Compounds: Short, Enantioselective, Gram-Scale Synthetic Entry into the Hapalindole and Fischerindole Alkaloid Families, J. Am. Chem. Soc. 2004, 126, 7450-7451. [Supporting Information]
 
Sceptrin43. Baran, P.S.; O'Malley, D.P.; Zografos, A.L. Sceptrin as a Potential Biosynthetic Precursor to Complex Pyrrole-Imidazole Alkaloids: The Total Synthesis of Ageliferin, Angew. Chem. Int. Ed. 2004, 43, 2674-2677.  [Supporting Information 1.4MB]
 
42. Baran, P.S.; Zografos, A.L.; O'Malley, D.P. Short Total Synthesis of Sceptrin, J. Am. Chem. Soc. 2004, 126, 3726-3727. [Supporting Information 1.5MB]
 
41. Baran, P. S.; Guerrero, C. A.; Corey, E. J. The First Method for Protection-Deprotection of the Indole 2,3-π Bond, Org. Lett. 2003, 5, 1999 - 2001.
40. Baran, P. S.; Guerrero, C. A.; Corey, E. J. A Short, Enantioselective Total Synthesis of Okaramine N, J. Am. Chem. Soc. 2003, 125, 5628 - 5629.
39. Nicolaou, K.C.; Baran, P.S. The CP-Molecules Labyrinth: How Endeavors in Total Synthesis Lead to Discoveries and Inventions in Organic Synthesis, Angew. Chem. Int. Ed. 2002, 41, 2678 - 2720.
38. Baran, P. S.; Corey, E. J. A Short Synthetic Route to (+)-Austamide, (+)-Deoxyaustamide, and (+)-Deoxyisoaustamide from a Common Preecursor by a Novel Palldium-Mediated Indole to Dihydroindoloazocine Cyclization, J. Am. Chem. Soc. 2002, 124, 7904 - 7905.
37. Nicolaou, K.C.; Montagnon, T.; Baran, P.S. HIO3 and I2O5: Mild and Selective Alternatives Reagents to IBX for the Dehydrogenation of Aldehydes and Ketones, Angew. Chem. Int. Ed. 2002, 41, 1386-1389.
36. Nicolaou, K.C.; Montagnon, T.; Baran, P.S. Modulation of the Reactivity Profile of IBX by Ligand Complexation: Ambient Temperature Dehydrogenation of Aldehydes and Ketones to a,b-Unsaturated Carbonyl Compounds, Angew. Chem. Int. Ed. 2002, 41, 993 - 996.
35. Nicolaou, K.C.; Jung, J.; Yoon, W. H.; Fong, K. C.; Choi, H. ¡VS.; He, Y.; Zhong, Y. L.; Baran, P. S. Total Synthesis of the CP-Molecules (CP-263,114 and CP-225,917, Phomoidrides B and A). Part 1. Racemic and Asymmetric Synthesis of Bicyclo(4.3.1) Key Building Blocks, J. Am. Chem. Soc. 2002, 124, 2183 - 2189.
34. Nicolaou, K.C.; Baran, P. S., Zhong, Y. L.; Fong, K. C.; Choi, H. ¡VS. Total Synthesis of the CP-Molecules (CP-263,114 and CP-225,917, Phomoidrides B and A). Part 2. Model Studies for the Construction of Key Structural Elements and First Generation Strategy, J. Am. Chem. Soc. 2002, 124, 2190 - 2201.
33. Nicolaou, K.C.; Zhong, Y. L.; Baran, P. S.; Jung, J.; Choi, H. ¡VS.; Yoon, W. H. Total Synthesis of the CP-Molecules (CP-263,114 and CP-225,917, Phomoidrides B and A). Part 3. Completion and Synthesis of Advanced Analogs, J. Am. Chem. Soc. 2002, 124, 2202 - 2211.
32. Nicolaou, K.C.; Baran, P. S.; Zhong, Y. L.; Sugita, K. Iodine(V)-Reagents in Organic Synthesis. Part 1. Synthesis of Polycyclic Heterocycles via DMP-Mediated Cascade Cyclization: Generality, Scope and Mechanism of the Reaction, J. Am. Chem. Soc. 2002, 124, 2212 - 2220.
31. Nicolaou, K.C.; Sugita, K.; Baran, P. S.; Zhong, Y. L. Iodine (V)-Reagents in Organic Synthesis. Part 2. Access to Complex Molecular Architectures via DMP-Generated o-Imidoquinones, J. Am. Chem. Soc. 2002, 124, 2221 - 2232.
30. Nicolaou, K.C.; Baran, P. S.; Zhong, Y. L.; Barluenga, S.; Hunt, K. W.; Kranich, R.; Vega, J. A. Iodine(V) Reagents in Organic Synthesis. Part 3. New Routes to Heterocyclic Compounds via IBX-Mediated Cyclizations: Generality, Scope, and Mechanism, J. Am. Chem. Soc. 2002, 124, 2233 - 2244.
29. Nicolaou, K.C.; Montagnon, T.; Baran, P. S.; Zhong, Y. L. Iodine(V)-Reagents in Organic Synthesis. Part 4. IBX as a Chemospecific Tool for SET-Based Oxidation Processes, J. Am. Chem. Soc. 2002, 124, 2245 - 2258.
28. Nicolaou, K.C.; Montagnon, T.; Ulven, T.; Baran, P. S.; Zhong, Y. L.; Sarabia, F. Novel Chemistry of £\-Sulfonated Ketones: Applications to the Solution and Solid Phase Synthesis of Privileged Heterocycle and Enediyne Libraries, J. Am. Chem. Soc. 2002, 124, 5718 - 5728.
27. MacMahon, S.; Fong, R.; Baran, P.S.; Safonov, I.; Wilson, S.R.; Schuster, D.I. Synthetic Approaches to a Variety of Covalently Linked Porphyrin-Fullerene Hybrids J. Org. Chem. 2001, 66; 5449-5455.
26. Nicolaou, K.C.; Baran, P.S.; Zhong, Y.L. Selective Oxidation at Carbon Adjacent to Aromatic Systems with IBX, J. Am. Chem. Soc. 2001, 123, 3183 - 3185.
25. Nicolaou, K.C.; Zhong, Y. L.; Baran, P.S.; Sugita, K. Rapid Access to Molecular Complexity via o-Azaquinones, Angew. Chem. Int. Ed. 2001, 40, 2145.
24. Wilson, S.R.; Baran, Phil S.; Schuster, D.I.; Goh, S.K.; Marynick, D.S. Theoretical and Experimental Studies of Fullerene and Nanotube Arene-chromium Complexes, manuscript in preparation.
23. Nicolaou, K.C.; Sugita, K.; Baran, P.S; Zhong, Y.-L. New Synthetic Technology for the Synthesis of Quinones Using DMP, Angew. Chem. Int. Ed. 2001, 40, 207-210.
22. Nicolaou, K.C.; Baran, P.S.; Kranich, R.; Zhong, Y.L.; Sugita, K.; Zou, N.; Mechanistic Studies of the Interactions of Periodinane Reagents with Anilides, Angew. Chem. Int. Ed. 2001, 40, 202-206.
21. Nicolaou, K.C.; Vourloumis, D.; Winssinger, N.; Baran, P.S. The Art and Science of Total Synthesis at the Dawn of the Twenty-first Century, Angew. Chem. Int. Ed. 2000, 39,44-122.
20. Nicolaou, K.C.; Baran, P.S.; Zhong, Y.L. Novel Solution and Solid Phase Chemistry of a-Sulfonated Ketones Applicable to Combinatorial Chemistry, J. Am. Chem. Soc. 2000, 122, 10246-10248.
19. Nicolaou, K.C.; Zhong, Y.-L.; Baran, Phil S. A New One-step Method for the Oxidation of Alcohols and Carbonyl Compounds to a,b-Unsaturated Systems, J. Am. Chem. Soc. 2000, 122, 7596-7597.
18. Nicolaou, K.C.; Baran, P.S.; Zhong, Y.-L.; Vega, J.A. Novel IBX-mediated Processes for the Synthesis of Amino Sugars and Libraries Thereof, Angew. Chem. Int. Ed. 2000, 39, 2525-2529.
17. Nicolaou, K.C.; Jung, J.-K.; Yoon, W.-Y.; He, Y.; Zhong, Y.-L.; Baran, P.S. The Absolute Configuration and Total Synthesis of the CP-molecules, Angew. Chem. Int. Ed. 2000, 39, 1829-1832.
16. Nicolaou, K.C.; Vassilikogiannakis, G.; Kranich, R.; Baran, P.S.; Zhong, Y.L.; Natarajan, S. New Synthetic Technology for the Mild and Selective Homologation of Hindered Aldehydes in the Presence of Ketones, Org. Lett. 2000, 2, 1895-1898.
15. Nicolaou, K.C.; Vassilikogiannakis, G.; Simonsen, K.B.; Baran, P.S.; Zhong, Y.-L.; Vidali, V.P.; Pitsinos, E.N.; Couladouros, E.A. Biomimetic Total Synthesis of Bisorbicillinol, Bisorbibutenolide, Trichodimerol and Designed Analogs of the Bisorbicillinoids, J. Am. Chem. Soc. 2000, 122, 3071 - 3079.
14. Baran, P.S.; Khan, A.U.; Schuster, D.I. Some Photophysical Properties of Nanotubes, Fullerene Sci. Tech. 1999, 7, 921-925.
13. Nicolaou, K.C.; Zhong, Y.-L.; Baran, P.S. New Synthetic Technology for the Rapid Construction of Novel Heterocycles. 1. The Reaction of Dess-Martin Periodinane with Anilides and Related Compounds, Angew. Chem. Int. Ed. 2000, 39, 622-625.
12. Nicolaou, K.C.; Zhong, Y.-L.; Baran, P.S. New Synthetic Technology for the Rapid Construction of Novel Heterocycles. 2. The Reaction of IBX with Anilides and Related Compounds, Angew. Chem. Int. Ed. 2000, 39, 625-628.
11. Nicolaou, K.C.; Jautelat, R.; Vassilikogiannakis, G.; Baran, P.S.; Simonsen, K. Studies towards Trichodimerol: Novel Cascade Reactions and Polycyclic Frameworks, Chem. Eur. J. 1999, 5, 3651-3665.
10. Nicolaou, K.C.; Simonsen, K.S.; Vassilikogiannakis, G.; Baran, P.S.; Vidali, V.P.; Pitsinos, E.N.; Couladouros, E.A. Biomimetic Explorations Towards the Bisorbicillinoids. Total Synthesis of Bisorbicillinol, Bisorbibutenolide and Trichodimerol, Angew. Chem. Int. Ed. 1999, 38, 3555-3559.
9. Nicolaou, K.C.; Baran, P.S.; Zhong, Y.-L.; Choi, H.-S.; Fong, K.C.; He, Y.; Yoon, W.H. New Synthetic Technology for the Synthesis of Hindered a-Diazoketones via Acyl Mesylates, Org. Lett. 1999, 1, 883-886.
8. Nicolaou, K.C.; Baran, P.S.; Zhong, Y.-L.; Choi, H.-S.; Yoon, W.H.; He, Y.; Fong, K.C. Total synthesis of the CP molecules CP-263,114 and CP-225,917- Part 1: Synthesis of Key Intermediates and Intelligence Gathering, Angew. Chem. Int. Ed. 1999, 38, 1669-1675.
7. Nicolaou, K.C.; Baran, P.S.; Zhong, Y.-L.; Fong, K.C.; He, Y.; Yoon, W.H.; Choi, H.S. Total Synthesis of the CP Molecules CP-263,114 and CP-225,917- Part 2: Evolution of the Final Strategy Angew. Chem. Int. Ed. 1999, 38, 1676-1678.
6. Nicolaou, K.C.; He, Y.; Fong, K.C.; Yoon, W.H.; Choi, H.-S.; Zhong, Y.-L.; Baran, P.S. Novel Strategies to Construct the g-Hydroxy Lactone Moiety of the CP Molecules. Synthesis of the CP-225,917 Core Skeleton. Org. Lett. 1999, 1, 63-66.
5. Nicolaou, K.C.; Baran, P.S.; Jautelat, R.; He, Y.; Fong, K.C.; Choi, H.-S.; Yoon, W.H.; Zhong, Y.-L. A Novel Route to the Fused Maleic Anhydride Moiety of CP Molecules. Angew. Chem. Int. Ed. 1999, 38, 549-552.
4. Schuster, D.I.; Baran, P.S.; Hatch, R.K.; Khan, A.U.; Wilson, S.R. The Role of Singlet Oxygen in the Photochemical Formation of C60O, Chem. Commun. (Cambridge) 1998, 22, 2493-2494.
3. Safonov, I.G.; Baran, P.S.; Schuster, D.I. Synthesis and Photophysics of a Novel Porphyrin-C60 Hybrid, Tetrahedron Lett. 1997, 38, 8133-8136.
2. Baran, P.S.; Monaco, R.R.; Khan, A.U.; Schuster, D.I.; Wilson, S.R. Synthesis and Cation-mediated Electronic Interactions of Two Novel Classes of Porphyrin-fullerene Hybrids, J. Am. Chem. Soc. 1997, 119, 8363-8364.
1. Baran, P.S.; Monaco, R.R.; Khan, A.U.; Schuster, D.I.; Soulas, P.; Echegoyen, L. Synthesis and Cation-mediated Electronic Interactions of Two Novel Classes of Porphyrin-fullerene Hybrids. Proc. - Electrochem. Soc. 1997, 97-14 (Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials), 25-36.